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Metal-catalyzed cross-coupling reactions are powerful and widespread methods for the carbon-carbon bond formation. Among the electrophile partners, non-activated alkyl halides remain challenging substrates because of their reluctance towards oxidative addi ...
The effect of reactor material (borosilicate and polyethylene terephthalate-PET) and its reuse on the microbiological and chemical decontamination of water by the photo-Fenton reaction at near-neutral pH was assessed. Escherichia coli was used as an indica ...
The thesis describes the utilization of dative boron-nitrogen bond is used for the construction of new materials. In chapter 2.1, the synthesis of new organogels based on bisimidazolyl ligands and diboronate esters is described. Gels with a critical gel co ...
Pure gallium and pure boron (PureGaB) Ge-on-Si photodiodes were fabricated in a CMOS compatible process and operated in linear and avalanche mode. Three different pixel geometries with very different area-to-perimeter ratios were investigated in linear arr ...
The photophysics and photochemistry of transition metal complexes (TMCs) has long been a hot field of interdisciplinary research. Rich metal-based redox processes, together with a high variety in electronic configurations and excited-state dynamics, have r ...
In this paper, we study tungsten oxides deposited by reactive magnetron sputtering. The total working pressure during deposition was varied in order to obtain different morphology. The effects on the electronic properties and chemical composition were stud ...
A novel strategy for post-synthesis amine borane functionalization of MOFs under gas-solid phase transformation, utilizing gaseous diborane, is reported. The covalently confined amine borane derivative decorated on the framework backbone is stable when pre ...
In this work, we show how to obtain efficient dynamic nuclear polarization (DNP) enhanced Cl-35 solid-state NMR (SSNMR) spectra at 9.4 T and demonstrate how they can be used to characterize the molecular-level structure of hydrochloride salts of active pha ...
The temperature-dependent flow behavior in nominally binary Al-Mg alloys measured recently (Jobba etal., 2015; Niewczas et al., 2015) is interpreted in the context of a parameter-free solute strengthening model. The recent measurements show consistently hi ...
The structural and electronic properties of a series of SrMnO3 thin films grown on different substrates leading to different biaxial strains are examined by means of aberration-corrected high-angle annular dark-field scanning transmission electron microsco ...