Publications associées à Équation d'Eyring

Mechanistic modelling of solar disinfection (SODIS) kinetics of Escherichia coli, enhanced with H2O2 - Part 2: Shine on you, crazy peroxide

César Pulgarin, Stefanos Giannakis, Ling Feng

In this second part of the development of a mechanistic kinetic model of the solar inactivation of E. coli enhanced with hydrogen peroxide, we evaluate the mechanisms based on photonic inactivation and integrate them into the kinetic model of the dark proc ...

ELSEVIER SCIENCE SA2022

Mechanistic modelling of solar disinfection (SODIS) kinetics of Escherichia coli, enhanced with H2O2 - part 1: The dark side of peroxide

César Pulgarin, Stefanos Giannakis, Ling Feng

The present bi-partite work describes the development and validation of a mechanistic kinetic model of SODIS E. coli inactivation, enhanced with H2O2. In this first part, the mechanism of the baseline dark phenomena is modelled. A mechanistic model involvi ...

ELSEVIER SCIENCE SA2022

A Precious Catalyst: Rhodium-Catalyzed Formic Acid Dehydrogenation in Water

Gabor Laurenczy, Cornel Fink

The performance of rhodium complex [Cp*Rh(bis(pyrazol-1-yl)methane)Cl]Cl was evaluated for formic acid dehydrogenation in aqueous solution. Solid-state X-ray diffraction helped to confirm the catalyst structure. Multinuclear NMR spectroscopy was employed t ...

WILEY-V C H VERLAG GMBH2019

Solar cooking potential in Switzerland: Nodal modelling and optimization

Andreas Schueler, Josef Andreas Schuler, Dasaraden Mauree, Olivia Valérie Charlotte Bouvard, Luc Burnier, Jérémy Jacques Antonin Fleury, Timothée Chatelain, Samson Taylor

Solar cooking is one possible solution to reduce the domination of fossil fuel in the domestic sector and to benefit from renewable energy. This study assesses the solar cooking potential in Switzerland. A nodal model, based on energy balance equations of ...

PERGAMON-ELSEVIER SCIENCE LTD2019

Combined Nuclear Magnetic Resonance and Molecular Dynamics Study of Methane Adsorption in M-2(dobdc) Metal-Organic Frameworks

Berend Smit, Efrem Daniel Braun, Rocio Mercado, Amber Kashan Mace

We examine the diffusion of methane in the metal organic frameworks M-2(dobdc) (M = Mg, Ni, Zn; dobdc(4-) = 2,5-diwddo-1,4-benzenedicarboxylate) as a function of methane loading through a combination of nuclear magnetic resonance and molecular dynamics sim ...

2019

Homogeneous Catalytic Formic Acid Dehydrogenation in Aqueous Solution using Ruthenium Arene Phosphine Catalysts

Gabor Laurenczy, Cornel Fink, Lu Chen

In this work, we studied catalytic formic acid dehydrogenation with a homogeneous RAPTA type precatalyst in aqueous solution. The effects of an amino group, attached to the arene, and the impact of a second equivalent of 1,3,5‐triaza‐7‐phosphaadamantane (P ...

2018

Computational support for a scaffolding mechanism of centriole assembly

Pierre Gönczy, Paul Guichard, Virginie Hamel

Centrioles are essential for forming cilia, flagella and centrosomes. Successful centriole assembly requires proteins of the SAS-6 family, which can form oligomeric ring structures with ninefold symmetry in vitro. While important progress has been made in ...

Nature Research2016

Effect of service temperature on the flexural creep of vacuum infused GFRP laminates used in sandwich floor panels

Thomas Keller, Mário Alexandre De Jesus Garrido

This paper presents an experimental and analytical study about the effect of temperature on the flexural creep of GFRP laminates produced by vacuum infusion. Such laminates are considered for use in the faces of sandwich panels for building floor applicati ...

Elsevier2016

Toward the correspondence between Q-clouds and sphalerons

Andrey Shkerin

Non-linear classical equations of motion may admit degenerate solutions at fixed charges. Whereas the solutions with lower energies are classically stable, those with larger energies are unstable and are referred to as Q-clouds. We consider a theory in whi ...

Elsevier2015

Capture and Release of CO2 in Monoethanolamine Aqueous Solutions: New Insights from First-Principles Reaction Dynamics

Wanda Andreoni, Changru Ma, Fabio Pietrucci

Aqueous,monoethanolamine (MEA) solution is commonly used for post-combustion carbon capture via chemical absorption. Extensive research has been carried out to characterize both uptake and release of carbon dioxide (CO2), with the aim of improving process ...

Amer Chemical Soc2015