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Ultrafast optical probing of the electric field by means of Stark effect in planar heterojunction cyanine dye / fullerene organic solar cells enables to directly monitor the dynamics of free electron formation during the dissociation of interfacial charge ...
Amer Chemical Soc2015
The metal-mediated redox transformation of CO2 in mild conditions is an area of great current interest. The role of cooperativity between a reduced metal center and a Lewis acid center in small-molecule activation is increasingly recognized, but has not so ...
2014
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Hydrogels are polymeric materials that have a relatively high capacity for holding water. Recently, a double network (DN) technique was developed to fabricate hydrogels with a toughness comparable to rubber. The mechanical properties of DN hydrogels may be ...
Amer Chemical Soc2016
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While phosphorescent cyclometalated iridium(III) complexes have been widely studied, only correlations between oxidation potential EOX and Hammett constant sigma, and between the redox gap (Delta E-REDOX = E-OX-E-RED) and emission or absorption wavelength ...
2014
We report on the spin dynamics and discovery of magnetoelectricity in the coupled-spin tetrahedral compound Cu2Te2O5Cl2. Te-125 NMR measurements show an anomalous resonance frequency shift and a signal wipe-out phenomenon around the Neel temperature T-N = ...
Amer Physical Soc2014
Long-range bonding interactions were evaluated using variable-temperature NMR spectroscopy and suitable 2'-CH2X-substituted phenylpyridines (X = Me, NMe2, OMe, F). It was found that the arylpyridyl rotational barriers were lower when electronegative atoms ...
Amer Chemical Soc2015
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Multimetallic cooperative binding of heteroallenes provides an attractive route to their activation, but the reduction of CS2 at heterobimetallic sites, associating an electron-rich metal with a main group Lewis acid has not been explored. Here we show tha ...
Royal Soc Chemistry2015
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The preparation and characterization of a series of complexes of the Yb and Eu cations in the oxidation state II and III with the tetradentate N,O-donor tripodal ligands (tris(2-pyridylmethyl)amine (TPA), BPA(-) (HBPA=bis(2-pyridylmethyl)(2-hydroxybenzyl)a ...
Second-order rate constants (k(O3)) for the reaction of ozone with micropollutants are essential parameters for the assessment of micropollutant elimination efficiency during ozonation in water and wastewater treatment. Prediction models for k(O3) were dev ...
This thesis deals with femtosecond broadband spectroscopy in the visible regime, which is used to study strongly correlated electron systems. The materials that were studied are high-temperature cuprate superconductors of various dopings and the charge-den ...
