Publications associées à Cyclohexane

Cycloalkane Oxidation Catalyzed by Copper-based Catalysts with H2O2 under Mild Conditions

Copper-catalyzed cycloalkane oxidation using H2O2 as an oxidant was investigated under mild conditions. The copper catalysts studied in this work ranged from commercially-available copper(II) salts to copper(II) complexes containing polypyridyl ligands. Va ...

WILEY-V C H VERLAG GMBH2023

Reduction of PdO/Al2O3 in Liquid Cyclohexane Followed In Situ by ATR-IR, High-Energy XRD, and XAS

Oliver Kröcher, Davide Ferri, Thibault Xavier Florian Fovanna

Supported Pd-based catalysts used in heterogeneously catalyzed liquid phase processes often undergo an activation step through reduction of the oxide phase or of the oxidic passivation layer prior to reaction. An oxidized Pd/Al2O3 catalyst was reduced by u ...

AMER CHEMICAL SOC2021

Valorization of biomass derivatives through the conversion of phenol over silica-supported Mo-Re oxide catalysts

Ricardo Javier Serpell Carriquiry

Liquid-phase hydrodeoxygenation of phenol over silica-supported MoOx-ReOx catalysts was investigated at 300 degrees C and 5 MPa of H-2. Mixed-oxides catalysts with similar surface metal density (2.3 atoms of metal per nm(2) of SiO2) but different relative ...

2020

Silicon Corrosion in Neutral Media: The Influence of Confined Geometries and Crevice Corrosion in Simulated Physiological Solutions

Stefano Mischler, Patrik Schmutz, Roland Hauert, Emilija Ilic

Silicon (Si) based implantable components are widely used to restore functionalities in the human body. However, there have been reported instances of Si corroding after only a few years of implantation. A key parameter often overlooked when assessing Si s ...

2019

Microstructural characterizations of 14Cr ODS ferritic steels subjected to hot torsion

Roland Logé

Oxide dispersion strengthened (ODS) steels are very promising materials for nuclear applications. In thispaper, the hot working behavior of ODS ferritic steels, consolidated by hot extrusion, is studied through torsion tests. Three ODS steels are produced ...

Elsevier2015

Oxygenated weathering products of Deepwater Horizon oil come from surprising precursors

Jonas Gros

Following the release of crude oil from the Macondo well in 2010, a wide range of weathering processes acted on the spilled oil. A recent study revealed that samples from this spill were oxidized into oxygenated hydrocarbons (OxHC) comprising more than 50% ...

Pergamon-Elsevier Science Ltd2013

{(1R,2R,4R)-4-Methyl-1,2-cyclohexanediamine}oxalatoplatinum(II): A Novel Enantiomerically Pure Oxaliplatin Derivative Showing Improved Anticancer Activity in Vivo

Christian Hartinger, Alexey Nazarov

Novel derivatives of the clinically established anticancer drug oxaliplatin were synthesized. Cytotoxicity of the compounds was studied in six human cancer cell lines by means of the MTT assay. Additionally, most promising complexes were also investigated ...

2010

How Strained are Carbomeric-Cycloalkanes?

Matthew Wodrich, Anne-Clémence Corminboeuf, Jérôme Florian Gonthier

The ring strain energies of carbomeric-cycloalkanes (molecules with one or more acetylene spacer units placed into carbon single bonds) are assessed using a series of isodesmic, homodesmotic, and hyperhomodesmotic chemical equations. Isodesmic bond separat ...

American Chemical Society2010

Synthesis and Conformational Analysis of (alpha-D-Galactosyl)phenylmethane and alpha-,beta-Difluoromethane Analogues: Interactions with the Plant Lectin Viscumin

Pierre Vogel, Maria Kolympadi

alpha-D-Galactosyl)phenylmethane (1). (alpha- and beta-D-galactosyl)-(difluoro)phenylmethane (2 and 3) have been prepared and their conformations in solution were described by using a combination of force-field calculations and NMR spectroscopic studies. G ...

2009