Craquage | EPFL Graph Search

Le craquage (cracking en anglais) est, en pétrochimie, la thermolyse du pétrole et de ses dérivés liquides. L'opération consiste à casser une molécule organique complexe en éléments plus petits, notamment des alcanes, des alcènes, des aldéhydes et des cétones. Les conditions de température et de pression, ainsi que la nature du catalyseur sont des éléments déterminants du craquage. En dehors de l'industrie pétrochimique, le craquage comprend toute dissociation induite d'une molécule (par exemple, le craquage de l'eau), à travers un processus tel que la thermolyse, la pyrolyse ou la photolyse. Historique En 1855, les premières méthodes de craquage du pétrole sont proposées par le professeur de chimie Benjamin Silliman, Jr. de la Sheffield Scientific School (SSS) à l'université Yale. La première méthode de craquage thermique, le procédé de craquage de Choukhov, a été inventée par l'ingénieur russe Vladimir Choukhov, dans l'Empire russe le . Eugène Houdry, un ingénieur f

Delayed Hydride Cracking in Irradiated and Unirradiated Zircaloy-2 Cladding

Aaron William Colldeweih

Zirconium alloys used in the nuclear industry are exposed to extreme conditions undergoing high levels of irradiation damage and corrosion. Zircaloy-2 is used as nuclear fuel cladding in boiling water reactors and for the encapsulation of the spallation target in the neutron source SINQ at the Paul Scherrer Institute. As a result of oxidation, hydrogen is produced and partially taken up into the zirconium matrix. As the hydrogen reaches the solubility limit, it precipitates in the form of a zirconium hydride. A number of deleterious effects of hydrides have been extensively studied, including the embrittlement of the material and a unique cracking phenomenon, namely delayed hydride cracking (DHC). DHC occurs as hydrogen in solid solution diffuses towards locations of higher tensile stress, where it subsequently precipitates as the local solvus limit is reached. Once the hydride grows to a critical size, it fractures, which can continue to propagate in repeated steps by the same mechanism.Several studies have been performed in order to understand properties of DHC based on parameters like, alloy type, cracking temperature, hydrogen content, and cracking direction. The most important mechanical properties include the fracture toughness and cracking velocity, which governs the material failure conditions. Crystallographic properties have been investigated in order to understand how complex hydride precipitation develops within the context of DHC conditions. In this project, radial DHC is explored in irradiated and unirradiated thin-walled Zircaloy-2 nuclear fuel cladding with and without an inner liner, in addition to spallation target rod material. A unique three-point bending test, applicable also for irradiated samples in the hotlab, was developed to induce a consistent radially propagating outside-in crack. Results have provided insight into the effects of the inner liner on cracking velocity, showing correlations with the hydrogen depletion. The combined DHC and creep mechanisms, which cannot be decoupled, is coined as âcreep-delayed hydride crackingâ. As the initiating conditions for DHC are of great technical importance, the threshold stress intensity factor has been investigated, under ideal DHC conditions, where a minimum value occurs around 6 MPaâm. Quantitative analysis of the hydrogen distribution around the tip of an arrested DHC crack tip has been performed with neutron radiography at the SINQ. Trends show that the hydrogen concentration around the crack tip increases with temperature resulting likely from the larger hydrogen diffusion, and that the liner reduces the hydrogen available for DHC. Crystallographic analysis has provided insight on the hydride phases responsible for DHC with synchrotron micro X-ray diffraction, performed at the Swiss Light Source at PSI. The results directly suggest that the Î³-hydride is a stable phase precipitated at low temperatures. Testing of irradiated material provided insight into the crack initiation of DHC as a result of the strongly irregular outer surface generated from the oxidation. The propagation pattern is highly irregular compared to the unirradiated material due to the embrittled nature of the cladding from irradiation damage.

EPFL2022

Stress Fields for the analysis of the faillure load and cracking state of dapped-end beams (Aplicación de modelos de campos de tensiones para el análisis en servicio y rotura de apoyos a media madera)

Miguel Fernández Ruiz, Jaime Mata Falcon, Aurelio Muttoni

The automatic generation of elastic-plastic stress fields (EPSF) for structural concrete members by means of the finite element method has been demonstrated as a suitable approach for the design and assessment of D regions. This methodology allows accounting for an elastic-plastic behaviour of the materials. For concrete, no tensile strength is considered, and the compression softening hypothesis of Vecchio & Collins is incorporated to take into account the effect of the transversal cracking on the compressive strength of concrete. In this paper, the application of this tool for the analysis of the failure load and cracking conditions at serviceability is investigated over a series of experimental tests on dapped-end beams (DEB). The failure of DEB occurred in most cases by spalling of the concrete cover on top of the suspension reinforcement. The models with the EPSF predicted also consistently this failure mode. Contrary to classical approaches of stress fields, where the tensile strength of the concrete cover is neglected (leading thus to conservative estimates of the strength for members failing by cover spalling), it is shown in this paper that EPSF can be suitably adapted to reproduce this failure mode by introducing a fictitious reinforcement in the cover. This reinforcement is introduced to reproduce cover spalling for a critical opening of the spalling cracks developing. With this assumption, a very good estimate of the experimental ultimate loads is consistently obtained, also for prestressed elements and for steel-fibre reinforced members (for which the contribution of the fibres is introduced in the model as an equivalent plastic tensile strength of the concrete). A methodology for the determination of the crack width in the critical regions of DEB for service load levels by using EPSF is also investigated. It is assumed a rigid-plastic approximation for the bond stresses near the crack. The methodology gives also reasonable and consistent estimates of the crack widths for DEB specimens, particularly for those with diagonal reinforcement, in which the cracking process is more stable.

VI Congreso ACHE2014

Structural condition assessment of reinforced-concrete bridges based on acoustic emission and strain measurements

Imane Bayane

A reliable novel monitoring approach is developed to assess the structural condition of reinforced-concrete bridge elements. The approach is based on combining acoustic emission technique and strain gauge measurements, and it is illustrated by a case study of a composite steel-concrete viaduct in service since 1957. Monitoring was performed on its reinforced-concrete deck slab under traffic and environmental loading for one year. The monitoring setup and procedure are presented. The variation of acoustic emission signals is evaluated regarding strain and temperature measurements. Parametric study, pencil-break test, statistical analysis, crack classification andb-value analysis are performed to assess the structural condition. The acoustic emission activity of the reinforced-concrete slab is evaluated for 1 year under operational conditions. From the monitoring approach, it was possible to identify the nature of the cracking activity in the concrete slab as a function of traffic loading and temperature and to assess in time the condition of the slab-girder connection.

2020

Delayed Hydride Cracking in Irradiated and Unirradiated Zircaloy-2 Cladding

Aaron William Colldeweih

EPFL2022

Miguel Fernández Ruiz, Jaime Mata Falcon, Aurelio Muttoni

VI Congreso ACHE2014