Concept

1,3-dipôle

Publications associées (18)

Isolation, Characterisation and Reactivity of N-Heterocyclic Diazoolefins

Examples for applications of nitrous oxide in organic synthesis remain rare up until today. First mayor contributions of our group were published in 2012, when nitrous oxide was successfully captured by N-heterocyclic carbenes. Subsequent studies investiga ...

EPFL2022

Applying dimension reduction to EEG data by Principal Component Analysis reduces the quality of its subsequent Independent Component decomposition

Fiorenzo Artoni

Independent Component Analysis (ICA) has proven to be an effective data driven method for analyzing EEG data, separating signals from temporally and functionally independent brain and non-brain source processes and thereby increasing their definition. Dime ...

2018

Scrape-off-layer current loops and floating potential in limited tokamak plasmas

Paolo Ricci, Joaquim Loizu Cisquella, Paola Paruta, Federico David Halpern

We investigate the question of how plasma currents circulate and close in the scrape-off-layer (SOL) of convection-limited tokamak plasmas. A simplified two-fluid model describes how currents must evacuate charge at the sheaths due to cross-field currents ...

Cambridge University Press2017

Exciting Wide NMR Spectra of Static Solid Samples with Weak Radiofrequency Fields

Geoffrey Bodenhausen, Diego Carnevale, Srinivas Chinthalapalli

Trains of short pulses in the manner of `delays alternating with nutations for tailored excitation' (DANTE) have been applied to the Pake patterns of protons of water molecules trapped in a static powdered sample of barium chlorate monohydrate. The spin dy ...

Walter De Gruyter Gmbh2017

Chiral Phosphoric Acid-Catalyzed Enantioselective Formal [3+2] Cycloaddition of Azomethine Imines with Enecarbamates

Qian Wang, Jieping Zhu, Yang Wang

The first catalytic asymmetric inverse electron demand 1,3-dipolar cycloaddition of azomethine imines with enecarbamates has been developed. Isoquinolinefused pyrazolidines containing two or three contiguous stereogenic centers were obtained in high yields ...

Wiley-Blackwell2016

Synthesis of Saturated Heterocycles via Metal-Catalyzed Formal Cycloaddition Reactions That Generate a C–N or C–O Bond

Jérôme Waser

In this section, the synthesis of saturated N- and O-heterocycles via formal cycloaddition is presented. The main focus is on metal-catalyzed reactions involving C–C or C–X σ bond cleavage in three- or four-membered rings. After a fast presentation of pion ...

Springer Verlag2013

Direct two-dimensional measurements of the eld-aligned current associated with plasma blobs

Ambrogio Fasoli, Ivo Furno, Christian Gabriel Theiler, Nicola Vianello

In simple magnetized toroidal plasmas, field-aligned blobs originate from ideal interchange waves and propagate radially outward under the effect of

\grad B

and curvature induced

E \times B

drifts. We report on the first experimental two-dimensional me ...

2011

A scaling factor theorem for homonuclear dipolar decoupling in solid-state NMR spectroscopy

David Lyndon Emsley

A relationship between the dipolar and the chemical-shift scaling factors of cyclic radio-frequency irradiation schemes is introduced. This scaling factor theorem is derived analytically using Average Hamiltonian Theory, and its validity is illustrated num ...

ACADEMIC PRESS INC ELSEVIER SCIENCE2011

Blob-induced toroidal momentum transport in simple magnetized plasmas

Ambrogio Fasoli, Ivo Furno, Paolo Ricci, Benoît Labit, Christian Gabriel Theiler

The link between toroidal flows and density blobs is experimentally demonstrated in TORPEX simple magnetized plasmas: momentum is transferred from an ideal-interchange mode to density blobs. The phase shift between the toroidal flow and the density perturb ...

American Institute of Physics2011

Computer simulation of uranyl uptake by the rough lipopolysaccharide membrane of pseudomonas aeruginosa

Matteo Guglielmi

Heavy metal environmental contaminants cannot be destroyed but require containment, preferably in concentrated form, in a solid or immobile form for recycling or final disposal. Microorganisms are able to take up and deposit high levels of contaminant meta ...

2008

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