Concept

Chlorure de fer(III)

Publications associées (63)

Arsenic sequestration by sorption processes in high-iron sediments

High-iron sediments in North Haiwee Reservoir (Olancha, CA), resulting from water treatment for removal of elevated dissolved arsenic in the Los Angeles Aqueduct system, were studied to examine arsenic partitioning between solid phases and porewaters under ...

2007

Mechanistic Studies on the Formation of eta(2)-Diphosphine (eta(6)-p-cymene)ruthenium(II) Compounds

Paul Joseph Dyson, Gabor Laurenczy, Céline Fellay

A new range of pendent diphosphine (η6-p-cymene)ruthenium(II) complexes, [RuCl(PPh3)(η1-(P-P))(η6-p-cymene)]PF6 (P-P = dppm, cis-PPh2CHCHPPh2

2007

Catalytic hydrogenation of alkenes under biphasic conditions

Corinne Daguenet

Ruthenium(II)-arene diphosphine complexes are shown to be effective precursors for the catalytic hydrogenation of the C=C bond in an aqueous biphase using molecular hydrogen as the hydrogen source. A mechanistic study performed in water, utilizing high gas ...

EPFL2006

Development of Organometallic Ruthenium-Arene Anticancer Drugs That Resist Hydrolysis

Paul Joseph Dyson, Wee Han Ang, Claudine Scolaro, Elisa Daldini

With a view to develop drugs that could resist hydrolysis in aq. media,organometallic arene-capped ruthenium(II) 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (RAPTA) complexes bearing chelating carboxylate ligands have been prepd. and studied. The new com ...

2006

Inhibition of catalytic activity in ionic liquids: Implications for catalyst design and the effect of cosolvents

Paul Joseph Dyson, Corinne Daguenet

As a consequence of inherently weak interactions between the chloride anion and the 1-butyl-3-methylimidazolium cation (ca. 15 kJ/mol), chloride dissociation from a transition-metal complex can be thermodynamically disfavored in ionic liquids. Therefore, w ...

2004

Abatement of an Azo Dye on Structured C-Nafion/Fe-Ion Surfaces by Photo-Fenton Reactions Leading to Carboxylate Intermediates with a Remarkable Biodegradability Increase of the Treated Solution

Lioubov Kiwi, Juan Kiwi, Sandra Parra Cardona

A novel C-Nafton/Fe-ion structured fabric capable of mediating Orange II decomposition in Fenton-immobilized photoassisted reactions is presented. The catalyst preparation requires the right balance between the amount of the Nafion necessary to protect the ...

2003

A comparison of ruthenium-catalysed arene hydrogenation reactions in water and 1-alkyl-3-methylimidazolium tetrafluoroborate ionic liquids

Paul Joseph Dyson, Gabor Laurenczy, William Henderson

The hydrogenation of benzene and other arene substrates under biphasic conditions is evaluated using the catalyst precursor Ru(eta(6)-C10H14)(pta)Cl-2 (pta = 1,3,5-triaza-7-phosphaadamantane) immobilised in water and 1-alkyl-3-methylimidazolium tetrafluoro ...

2003

Response Mechanism of Anion-Selective Electrodes Based on Mercury Organic Compounds as Ionophores

New mercury organic compounds with 1-3 metal centers and different substituents were synthesized as anion-selective ionophores. They were incorporated into solvent polymeric membranes, and the selectivity, slope of response, response time, emf repeatabilit ...

1996

Behavior of various arsenic species in electrothermal atomic absorption spectrometry

The behavior of arsenite (AsIII), arsenate (AsV), monomethylarsonate (MMA), dimethylarsinate (DMA), arsenobetaine (AsB) and arsenocholine (AsC) in pyrolytic graphite coated graphite (pyrocoated) tubes was studied. The influence of a tungsten carbide coatin ...

1996

A convenient and economic way to produce anhydrous hydrogen bromide

Bromide promoted decompn. of tert-Bu bromide in the presence of triphenylphosphine gives, besides isobutene, hydrogen(triphenyl)phosphonium bromide. When heated to approx. 150 DegC in the presence of xylene, the latter salt liberates hydrogen bromide which ...

1994

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