Publications associées à Propriété colligative

Using continuous electrical conductivity measurements to derive major solute concentrations in karst systems

Hydrochemical data of karst springs provide valuable insights into the internal hydrodynamical functioning of karst systems and support model structure identification. However, the collection of high-frequency time series of major solute species is limited ...

WILEY2023

The Height of Chitinous Ridges Alone Produces the Entire Structural Color Palette

Hemant Kumar Raut

The colorful wings of butterflies result from the interaction between light and the intricate chitinous nanostructures on butterflies’ scales. This study demonstrates that just by reproducing the chitinous ridges present in butterfly scales (i.e., without ...

2022

Quantitative electronic structure and work-function changes of liquid water induced by solute

Bruno Credidio

Recent advancement in quantitative liquid-jet photoelectron spectroscopy enables the accurate determination of the absolute-scale electronic energetics of liquids and species in solution. The major objective of the present work is the determination of the ...

ROYAL SOC CHEMISTRY2022

Water Activity from Equilibrium Molecular Dynamics Simulations and Kirkwood-Buff Theory

Satoshi Takahama, Mária Lbadaoui-Darvas

Water activity and related thermodynamic properties are calculated for several aqueous solutions using equilibrium molecular dynamics in conjunction with the recent extension of the Kirkwood-Buff (KB) theory for closed systems. The general applicability of ...

AMER CHEMICAL SOC2019

In Situ Liquid SAXS Studies on the Early Stage of Calcium Carbonate Formation

Andrea Testino, Mohammad Reza Andalibi, Agnese Carino

Calcium carbonate is a model system to investigate the mechanism of solid formation by precipitation from solutions, and it is often considered in the debated classical and nonclassical nucleation mechanism. Despite the great scientific relevance of calciu ...

2019

Unsupervised Robust Nonparametric Learning Of Hidden Community Properties

Martin Jaggi, Akhilesh Deepak Gotmare, Mikhail Langovoy

We consider learning of fundamental properties of communities in large noisy networks, in the prototypical situation where the nodes or users are split into two classes according to a binary property, e.g., according to their opinions or preferences on a t ...

2019

The Jones–Ray Effect Is Not Caused by Surface-Active Impurities

Sylvie Roke, Halil Ibrahim Okur, Eric Tyrode

Pure aqueous electrolyte solutions display a minimum in surface tension at concentrations of 2 ± 1 mM. This effect has been a source of controversy since it was first reported by Jones and Ray in the 1930s. The Jones–Ray effect has frequently been dismisse ...

2018

Decomposing the Bulk Electrical Conductivity of Streamflow To Recover Individual Solute Concentrations at High Frequency

Paolo Benettin

The ability to evaluate stream hydrochemistry is often constrained by the capacity to sample streamwater at an adequate frequency. While technology is no longer a limiting factor, costs and sample management can still be a barrier to high-resolution water ...

Amer Chemical Soc2017

Strengthening of high entropy alloys by dilute solute additions: CoCrFeNiAlx and CoCrFeNiMnAlx alloys

William Curtin, Céline Varvenne

A theory to predict the initial flow stress of an arbitrary N-component fcc random alloy is extended to predict the additional strengthening when a dilute concentration of a substitutional element is introduced. Assuming properties for the N-component allo ...

2017

Rich Vehicle and Inventory Routing Problems with Stochastic Demands

Iliya Dimitrov Markov

This thesis develops a unified framework for modeling and solving various classes of rich routing problems with stochastic demands, including the VRP and the IRP. The work is inspired by the problem of collecting recyclables from sensorized containers in G ...

EPFL2017