Concept

Périclase

Publications associées (18)

High Sodium Solubility in Magnesiowüstite in Iron-Rich Deep Lower Mantle

Marco Cantoni, James Badro, Susannah McGregor Dorfman, Farhang Nabiei

(Mg,Fe)O ferropericlase-magnesiow & uuml;stite has been proposed to host the majority of Earth's sodium, but the mechanism and capacity for incorporating the alkali cation remain unclear. In this work, experiments in the laser-heated diamond anvil cell and ...

Amer Geophysical Union2024

First-Principles Thermodynamics of CsSnI3

Nicola Marzari, Lorenzo Monacelli

CsSnI3 is a promising ecofriendly solution for energy harvesting technologies. It exists at room temperature in either a black perovskite polymorph or a yellow 1D double-chain, which irreversibly deteriorates in the air. In this work, we unveil the relativ ...

AMER CHEMICAL SOC2023

Ferroelectric Effects Probed by in situ Transmission Electron Microscopy

Reinis Ignatans

Ferroelectric perovskite oxides are widely used in sensors, actuators and optical modulators and, at the same time, they show promise for implementation in future applications such as energy storage, memory and cooling devices. At the infancy of the discov ...

EPFL2022

Segregation of Nickel/Iron Bimetallic Particles from Lanthanum Doped Strontium Titanates to Improve Sulfur Stability of Solid Oxide Fuel Cell Anodes

Davide Ferri, Oliver Kröcher, Andre Heel

Perovskite derived Ni catalysts offer the remarkable benefit of regeneration after catalyst poisoning or Ni particle growth through the reversible segregation of Ni from the perovskite-type oxide host. Although this property allows for repeated catalyst re ...

MDPI2019

Structural Reversibility and Nickel Particle stability in Lanthanum Iron Nickel Perovskite-Type Catalysts

Davide Ferri, Oliver Kröcher, Debora Foppiano, Andre Heel

Perovskite-type oxides have shown the ability to reversibly segregate precious metals from their structure. This reversible segregation behavior was explored for a commonly used catalyst metal, Ni, to prevent Ni sintering, which is observed on most catalys ...

Wiley-V C H Verlag Gmbh2017

Understanding the nature of atmospheric acid processing of mineral dusts in supplying bioavailable phosphorus to the oceans

Athanasios Nenes

Acidification of airborne dust particles can dramatically increase the amount of bioavailable phosphorus (P) deposited on the surface ocean. Experiments were conducted to simulate atmospheric processes and determine the dissolution behavior of P compounds ...

National Academy of Sciences2016

Spin state transition and partitioning of iron: Effects on mantle dynamics

James Badro

Experimental studies at pressure and temperature conditions of the Earth's lower mantle have shown that iron in ferropericlase (Fp) and in Mg-silicate perovskite (Pv) undergoes a spin state transition. This electronic transition changes elastic and transpo ...

Elsevier2015

Spin Transitions in Mantle Minerals

James Badro

Mantle minerals at shallow depths contain iron in the high-spin electronic state. The crystal-field splitting energy increases with increasing pressure, which can favor the low-spin state. Hence, pressure-driven transitions from the high-spin to the low-sp ...

Annual Reviews2014

Fe-containing phases in hydrated cements

Karen Scrivener, Barbara Lothenbach, Belay Zeleke Dilnesa

In this study synchrotron X-ray absorption spectroscopy (XAS) has been applied, an element specific technique which allows Fe-containing phases to be identified in the complex mineral mixture of hydrated cements. Several Fe species contributed to the overa ...

Elsevier2014

Effect of Fe-enrichment on seismic properties of perovskite and post-perovskite in the deep lower mantle

Susannah McGregor Dorfman

Recent experimental measurements of the equation of state of perovskites and post-perovskites in the (Mg,Fe)SiO3 and (Mg,Fe,Al)(Fe,Al,Si)O-3 systems over a wide range of iron contents are used to constrain the effects of Fe and Al on density and bulk modul ...

Oxford University Press2014

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