Concept

Coordination polymer

Publications associées (176)

Quantifying similarity of pore-geometry in nanoporous materials

Berend Smit, Kathryn Hess Bellwald, Senja Dominique Barthel, Yongjin Lee, Pawel Tadeusz Dlotko

In most applications of nanoporous materials the pore structure is as important as the chemical composition as a determinant of performance. For example, one can alter performance in applications like carbon capture or methane storage by orders of magnitud ...

Nature Publishing Group2017

Rising Stars in Science and Technology: Luminescent Lanthanide Materials

Jean-Claude Bünzli

This essay draws attention to lanthanide luminescence by putting into perspective the sensitization process of f-f emission, the design of highly luminescent lanthanide-based compounds, and upconversion nanoparticles. A brief overview of the recent advance ...

Wiley-V C H Verlag Gmbh2017

Natural inspirations for metal–ligand cooperative catalysis

Xile Hu, Matthew Wodrich

In conventional homogeneous catalysis, supporting ligands act as spectators that do not interact directly with substrates. However, in metal–ligand cooperative catalysis, ligands are involved in facilitating reaction pathways that would be less favourable ...

2017

Natural inspirations for metal–ligand cooperative catalysis

Xile Hu, Matthew Wodrich

2017

Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands

Rosario Scopelliti, Kay Severin, Henrik Moodysson Rønnow, Ivica Zivkovic, Philip Pattison, Bálint Náfrádi, Euro Solari, Giacomo Cecot, Mathieu Jérémie Marmier, José Luis Bila

Dinuclear clathrochelate complexes with two, three, four, or five cyano groups in the ligand periphery were prepared following two distinct synthetic strategies: (a) zinc(II)- or cobalt(II)-templated polycondensation reactions of CN-functionalized arylboro ...

Royal Society of Chemistry2016

On-Surface Assembly and Reactions of Organic Molecules in Ultra-High Vacuum

Claudius Morchutt

This thesis comprises the study of two types of 2D materials, those stabilized by non-covalent and those by covalent interactions. They are synthesized and studied on well-defined metallic surfaces in ultra-high vacuum (UHV). The self-assembly of terephtha ...

EPFL2016

Functionalized Dinuclear Clathrochelates as Supramolecular Building Blocks

Mathieu Jérémie Marmier

This thesis details the synthesis and characterization of dinuclear clathrochelates functionalized with groups suitable for supramolecular applications. Their successful incorporation into self-assembled discrete and polymeric structures is related. These ...

EPFL2016

Two-dimensional metal-organic networks as templates for the self-assembly of atom and cluster arrays

Giulia Elisabetta Pacchioni

This thesis presents a study of the use of two-dimensional metal-organic systems as templates for the organization of metal atoms and clusters on surfaces. We start with a systematic characterization of the metal-organic porous networks formed on Cu(111) b ...

EPFL2016

Driving the Oxygen Evolution Reaction by Nonlinear Cooperativity in Bimetallic Coordination Catalysts

Klaus Kern, Benjamin Wurster

Developing efficient catalysts for electrolysis, in particular for the oxygen evolution in the anodic half cell reaction, is an important challenge in energy conversion technologies. By taking inspiration from the catalytic properties of single-atom cataly ...

Amer Chemical Soc2016

Interplay of Chemical and Electronic Structure on the Single-Molecule Level in 2D Polymerization

Klaus Kern, Claudius Morchutt, Carola Strasser

Single layers of covalently linked organic materials in the form of two-dimensional (2D) polymers constitute structures complementary to inorganic 2D materials. The electronic properties of 2D polymers may be manipulated through a deliberate choice of the ...

American Chemical Society2016

Graph Chatbot

Chattez avec Graph Search

Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.

AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.

Connectez-vous pour utiliser Chat avec Graph Search