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The utilization of silicon-based polymers as a source of amorphous non-oxide ceramics obtained upon pyrolytic treatment of them is increasingly gaining attention in research and is currently expanding into the field of commercial products. This work is foc ...
Hot tearing and loss of dimensional stability are two key defects related to industrial aluminum alloy casting processes. In order to investigate their occurrence, a new semi-solid constitutive law [20] for AA5182 that takes into account cooling rate, grai ...
TMS (The Minerals, Metals & Materials Society)2012
The BaylisHillman reaction provides a protective-group-free strategy to heterobifunctional polyesters, which can be further modified via various post-polymerization modification reactions. This contribution explores the BaylisHillman polymerization of 1,3- ...
The average lifetime of an implanted pacemaker or defibrillator cable (lead) is approximately 10 years. One of the main lead failure mechanisms is deterioration of the insulation, which can be caused by chemical, biological, and mechanical processes. Each ...
Aliphatic polyesters receive increasing attention over the last years driven by their application as biodegradable substitutes for conventional commodity thermoplastics and applications in the biomedical field, where amongst the family of biodegradable pol ...
Introduction of highly reactive vinyl ether moieties along a poly(ethylene-glycol) (PEG) backbone has been realized by copolymerization of the novel epoxide monomer ethoxy vinyl glycidyl ether (EVGE) with ethylene oxide (EO). A series of copolymers with va ...
The cost-effective production of high-performance and durable steel reinforced thermoplastic composites requires improvement of the adhesion encountered at the interface between metallic substrates (galvanized steel) and a thermoplastic elastomer (TPU). Co ...
Dynamic Mechanical Analysis was conducted on a polyurethane adhesive at different constant heating rates up to 100°C, covering the glass transition range. Different storage modulus degradation curves were obtained from different heating rates. The differen ...
When a thermoplastic polyurethane elastomer (TPU) is co-molded with galvanized steel, the subsequent adhesion and its durability are very sensitive to the chemical bonds created at the interface. Silane coupling primers are known for enhancing adhesion bet ...
Strategies that allow access to side-chain functional polyesters are valuable as they would enable to engineer the properties of these hydrolytically degradable materials. This contribution explores the feasibility of a novel approach toward side-chain fun ...
