Publications associées à Hapticité

A five-stranded heterometallic helicate

Kay Severin, Farzaneh Fadaei Tirani, Sylvain Alexandre Marie Sudan

A penta-stranded helicate was obtained by combining Pd(CH3CN)42 with La(NO3)3 and a polydentate ligand. The helicate displays low symmetry, both in solution and in the solid state. A dynamic interconversion between the penta-stranded helicate and a ...

Royal Society of Chemistry2023

Tuning the structural and antiferromagnetic phase transitions in UCr2Si2: Hydrostatic pressure and chemical substitution

Philip Johannes Walter Moll

Structural phase transitions in f-electron materials have attracted sustained attention both for practical and basic science reasons, including the fact that they offer an environment to directly investigate relationships between structure and the f-state. ...

2020

Carbon dioxide reduction by dinuclear Yb(ii) and Sm(ii) complexes supported by siloxide ligands

Marinella Mazzanti, Farzaneh Fadaei Tirani, Davide Toniolo

Two dinuclear homoleptic complexes of lanthanides(II) supported by the polydentate tris(tertbutoxy) siloxide ligand ([Yb2L4], 1-Yb and [Sm2L4], 1-Sm, (L = (OtBu)3SiO−)) were synthesized in 70–80% yield and 1-Sm was crystallographically characterized. 1-Yb ...

2019

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone

Here we show that a scaffold combining siloxide ligands and a bridging oxide allows the synthesis and characterization of the stable dinuclear uranium(IV) hydride complex [K-2{U(OSi((OBu)-Bu-t)(3))(3)(mu-O)(mu-H)(2)}], 2, which displays high reductive ...

2019

Fine-tuning the coordination atoms of copper redox mediators: an effective strategy for boosting the photovoltage of dye-sensitized solar cells

Ulf Anders Hagfeldt, Chong Liu, Mei Wang

Natural systems have marvelously utilized copper complexes featuring sulfur-coordinating ligands, known as blue copper proteins, as efficient electron-transfer mediators in biological processes. Copper complexes with sulfur-coordinating ligands have been a ...

Royal Society of Chemistry2019

A tetranuclear samarium(II) inverse sandwich from direct reduction of toluene by a samarium(II) siloxide

Marinella Mazzanti, Farzaneh Fadaei Tirani, Davide Toniolo, Rory Patrick Kelly

The dinuclear SmII complex, [Sm2L4(dme)] (L = OSi(OtBu)3), is easily obtained from the protonolysis reaction of [Sm{N(SiMe3)2}(thf)2] with HOSi(OtBu)3. This complex reacts slowly with toluene, resulting in the isolation of the triple-decker arene-bridged S ...

2018

Features of proteolytic properties of tetraphenylporphyrin complex with lanthanide group metals

Demetallation of metalloporphyrin molecules is one of the essential degradation reactions in photosynthesis. The effect of metalloporphyrin nature on removal of central metals from tetraphenylporphyrin complexes based on lanthanide group metals (Dy, Er, Lu ...

2018

Highly selective immobilized bimetallic Ni-Au nanoparticle catalyst for the partial hydrogenation of m-dinitrobenzene

Paul Joseph Dyson, Lioubov Kiwi, Oliver Anthony Beswick, Fernando Cardenas Lizana, Daniel André Samuel Lamey

Transition metal nanoparticles (NPs) are extensively used as catalysts for a wide and diverse range of organic transformations when immobilized on appropriate solid supports. We describe the development of a highly active and highly selective heterogeneous ...

Elsevier Science Bv2017

Synthesis and reactivity of a terminal uranium(IV) sulfide supported by siloxide ligands

Rosario Scopelliti, Marinella Mazzanti, Julie Renée Michelle Andrez

The reactions of the tetrasiloxide U(III) complexes [U(OSi(OtBu)3)4K] and [U(OSi(OtBu)3)4][K18c6] with 0.5 equiv. of triphenylphosphine sulfide led to reductive S-transfer reactions, affording the U(IV) sulfide complexes [SU(OSi(OtBu)3)4K2]2, 1, and [{SU(O ...

2016

Low-voltage, high-brightness and deep-red light-emitting electrochemical cells (LECs) based on new ruthenium(II) phenanthroimidazole complexes

Mohammad Khaja Nazeeruddin, Cristina Roldán Carmona

Light-Emitting Electrochemical Cells (LECs) with a simple device structure ITO/Ru complex/Ga: In were prepared by using heteroleptic ruthenium(II) complexes containing 2-(2-hydroxyphenyl)-1(4-bromophenyl)-1h-imidazo[4,5-f][1,10] phenanthroline (hpbpip) as ...

Royal Society of Chemistry2016