Concept
Tosyle
Publications associées (27)
An explainability framework for deep learning on chemical reactions exemplified by enzyme-catalysed reaction classification
Assigning or proposing a catalysing enzyme given a chemical or biochemical reaction is of great interest to life sciences and chemistry alike. The exploration and design of metabolic pathways and the challenge of finding more sustainable enzyme-catalysed a ...
2023Improving visible light photocatalytic inactivation of E. coli by inducing highly efficient radical pathways through peroxymonosulfate activation using 3-D, surface-enhanced, reduced graphene oxide (rGO) aerogels
César Pulgarin, Stefanos Giannakis, Minoo Karbasi
In this work, we synthesized highly porous reduced graphene oxide foams, presenting augmented antibacterial activity in presence/absence of peroxymonosulfate (PMS). To date, this is the first investigation of photocatalytic PMS disinfection by 3D-rGO mater ...
ELSEVIER SCIENCE SA2020Production, characterization and upgrading of biomass-derived acetal-stabilized carbohydrates
Biomass is an attractive source of renewable carbon-based fuels and chemicals. Multiple research efforts are centered around integrated biorefineries, where all fractions of biomass are converted to fuels or chemical products. These efforts are focused aro ...
EPFL2019A facile synthetic strategy to polysiloxanes containing sulfonyl side groups with high dielectric permittivity
The chemical modification of polymers with lateral polar groups increases their dielectric permittivity above the glass transition temperature, making them attractive materials for dielectric elastomer actuators. Despite the large dipole moment of the sulf ...
Royal Society of Chemistry2017Kinetics and mechanisms of nitrate and ammonium formation during ozonation of dissolved organic nitrogen
Urs von Gunten, Glen Andrew De Vera
Dissolved organic nitrogen (DON) is an emerging concern in oxidative water treatment because it exerts oxidant demand and may form nitrogenous oxidation/disinfection by-products. In this study, we investigated the reactions of ozone with DON with a special ...
Elsevier2017trans-Mutation at Gold(III): A Mechanistic Study of a Catalytic Acetylene Functionalization via a Double Insertion Pathway
The Au(III) complex Au(tpy)(OAcF)2 (OAcF = OCOCF3; tpy = 2-(p-tolyl)pyridine) catalyzes the anti addition of trifluoroacetic acid (HOAcF) to acetylene to furnish vinyl trifluor- oacetate. The Au(III) vinyl complex Au(tpy)(OAcF)(CHCHOAcF) (vinyl group bond ...
American Chemical Society2017Synthesis of cyclic peptide disulfide-PHPMA conjugates via sequential active ester aminolysis and CuAAC coupling
Cyclic peptide disulfides (CXC) are an important class of biomolecules. The conjugation of cyclic peptide disulfides to synthetic polymers, however, is often difficult due to the presence of the disulfide bond combined with other potentially reactive side ...
Royal Society of Chemistry2016