Concept
Mutarotation
Publications associées (4)
Cryogenic Ion Spectroscopy for Identification of Monosaccharide Anomers
Thomas Rizzo, Valeriu Scutelnic
We combine conformer-selective, cryogenic infrared spectroscopy, quantum mechanical computations, and 18O substitution at the reducing end to determine the structural preferences of protonated glucosamine in the gas phase. Cryogenic infrared-infrared (IR-I ...
2019Synthesis of C-glycosides and C-linked disaccharides through carbonylative Stille coupling reactions
In the first part, we described the synthesis of C-(1'→1) and C-(1'→4) disaccharide precursors, which are readily obtained via the carbonylative Stille coupling of glucal and isolevoglucosenone derivatives. Tin glycals and triflates, derived from isolevogl ...
EPFL2005The kinetics of lactose hydrolysis for the b-galactosidase from Aspergillus niger
The kinetics of glucose liberation from lactose by b-galactosidase from A. niger was studied in a wide range of the main variables. The anal. shows that the kinetic models proposed so far are not adequate. The main finding is that the reaction rate is not ...
1982