Clathrate hydrate

Science de la nature
Astronomie
Planétologie
Atmosphère planétaire

Publications associées (31)

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Observation of methane filled hexagonal ice stable up to 150 GPa

Philippe Gillet, Richard Gaal, Livia Eleonora Bove Kado, Umbertoluca Ranieri

Gas hydrates consist of hydrogen-bonded water frameworks enclosing guest gas molecules and have been the focus of intense research for almost 40 y, both for their fundamental role in the understanding of hydrophobic interactions and for gas storage and ene ...

National Academy of Sciences2019

Factors influencing the hydration kinetics of ye'elimite; effect of mayenite

Karen Scrivener, Mohsen Ben Haha, Frank Bullerjahn

The aim of this study was to understand the origin of the variation in the hydraulic reactivity of ye'elimite systems. To this end, the hydration of two clinkers, one composed mainly of synthetic stoichiometric (C(4)A(3)(S) over bar) "Y" and the other of a ...

Pergamon-Elsevier Science Ltd2019

Hydration reactions and stages of clinker composed mainly of stoichiometric ye'elimite

Karen Scrivener, Emmanuelle Boehm Courjault, Mohsen Ben Haha, Frank Bullerjahn

Ye'climitc (Ca4Al6O12SO4 or C(4)A(3)(S) over bar) is the main hydraulic mineral present in calcium sulfoaluminate cement (CSA). The hydration of ye'elimite is responsible for the early age cement properties. We identify 5 stages in the hydration of neat st ...

Pergamon-Elsevier Science Ltd2019

Salt- and gas-filled ices under planetary conditions

Livia Eleonora Bove Kado, Umbertoluca Ranieri

In recent years, evidence has emerged that solid water can contain substantial amounts of guest species, such as small gas molecules-in gas hydrate structures-or ions-in salty ice structures-and that these 'filled' ice structures can be stable under pressu ...

ROYAL SOC2019

Quantum Dynamics of H-2 and D-2 Confined in Hydrate Structures as a Function of Pressure and Temperature

Philippe Gillet, Richard Gaal, Livia Eleonora Bove Kado, Umbertoluca Ranieri

We present an extensive study of the quantum dynamics of molecular hydrogen trapped within the nanocavities of two hydrate structures at low temperatures, namely, clathrate structure II and filled ice structure Cl. By inelastic neutron scattering measureme ...

AMER CHEMICAL SOC2019

Kinetics of mixing-water repartition in UHPFRC paste and its effect on hydration and microstructural development

Eugen Brühwiler, Karen Scrivener, Emmanuel Denarié, Arnaud Charles Albert Muller, Mohammadhadi Kazemi Kamyab

The hydration of an ultra-high performance fibre reinforced concrete (UHPFRC) paste with a water to cement ratio of 0.18 was followed by proton nuclear magnetic resonance (1H NMR) alongside more classical techniques for hydration kinetics, and microstructu ...

Pergamon-Elsevier Science Ltd2019

Chemical shrinkage of ye'elimite with and without gypsum addition

Karen Scrivener, Mohsen Ben Haha, Frank Bullerjahn

Ye'elimite (Ca4Al6O12SO4 or C(4)A(3)S) is the main hydraulic mineral present in calcium sulphoaluminate cement (CSA). Its reaction is responsible for the (early) hydration and associated cement properties such as the chemical shrinkage. This paper discusse ...

ELSEVIER SCI LTD2019

The influence of the filler effect on the sulfate requirement of blended cements

Karen Scrivener, Franco Alberto Zunino Sommariva

In some blended cements, the optimum amount of sulfate addition differs from that observed in OPC. This study aims to understand the mechanism behind the impact of two SCMs, namely metakaolin and limestone, on the sulfate balance of blended cements. No sig ...

Pergamon-Elsevier Science Ltd2019

Site Selective Detection of Methane Dissociation on Stepped Pt Surfaces

Rainer Beck, Ana Gutiérrez González

We report a combined experimental and theoretical study comparing methane dissociation on three di erent platinum surfaces Pt(111), Pt(211), and Pt(110)-(1 × 2). Re ection absorption infrared spectroscopy (RAIRS) was used to detect chemisorbed methyl speci ...

2019

Guest dynamics in methane hydrates and hydrogen hydrates under high pressure

Umbertoluca Ranieri

Hydrates of gas are non-stoichiometric inclusion compounds constituted of water and gas. Therein, the water molecules are hydrogen-bonded and form three-dimensional crystalline networks incorporating different kinds of polar or nonpolar guest gas molecules ...

EPFL2018

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