Universal wavefunction | EPFL Graph Search

The universal wavefunction (or wave function), introduced by Hugh Everett in his 1973 PhD thesis The Theory of the Universal Wave Function, informs a core concept in the relative state interpretation or many-worlds interpretation of quantum mechanics. It later received investigation from James Hartle and Stephen Hawking in which they derived a specific solution to the Wheeler–deWitt equation to explain the initial conditions of the Big Bang cosmology. Everett's thesis introduction reads: Since the universal validity of the state function description is asserted, one can regard the state functions themselves as the fundamental entities, and one can even consider the state function of the entire universe. In this sense this theory can be called the theory of the "universal wave function," since all of physics is presumed to follow from this function alone. The universal wave function is the wavefunction or quantum state of the totality of existence, regarded as the "basic physical en

Probing Entangled States of the Nuclear-Electronic Quantum Magnet LiHoF₄

Ivan Kovacevic

Two objects are entangled when their quantum mechanical wavefunctions cannot be written in a separable product form. Entangling dissimilar quantum objects, or hybridization, has been suggested as a promising route to efficient quantum information processors, but mostly realized on a limited scale. Hybrid nuclear-electronic many-body systems remain a largely unexplored challenge to both experiments and theories. The prototypical transverse-field Ising ferromagnet LiHoF4 is an ideal platform to address this issue. The Ising model is considered as an archetype both for the investigation of quantum criticality and for the evaluation of quantum simulators. The hyperfine coupling strength of a Ho ion is exceptionally large, promoting a strong hybridization or entanglement between the nuclear and electronic moments. The magnetic coupling between the Ho ions that leads to ferromagnetic ordering is predominantly through long-range dipole interactions, while nearest-neighbor exchange interaction is negligibly weak. Applying a transverse field induces a zero temperature quantum phase transition driven by quantum fluctuations. Altogether LiHoF4 represents a unique nuclear-electronic quantum magnet, whose wavefunctions can be readily obtained by diagonalizing the Hamiltonian using the mean-field approximation. In this thesis we develop an experimental setup to probe the entangled nuclear-electronic states in a model transverse-field Ising system LiHoF4. Using magnetic resonance the field and temperature evolution of the nuclear-electronic states are successfully traced across the whole phase diagram. We develop a theoretical framework based on mean-field calculations which provides close agreement with the experimental observations. Having established experimentally that the mean-field wavefunctions are an excellent approximation of the actual wavefunction, we used them to calculate the ground-state entanglement entropy between the electronic and nuclear magnetic moments. We find that the entanglement entropy between the nuclear and electronic moments exhibits a peak at the quantum phase transition. This suggests that the electronic entanglement is encoded onto each nuclear-electronic state. Our results pave the way for new theoretical and experimental investigations of quantum entanglement.

EPFL2016

Strongly bound excitons in anatase TiO2 single crystals and nanoparticles

Gerald Auböck, Edoardo Baldini, Helmuth Berger, Majed Chergui, Marco Grioni, Arnaud Magrez, Simon Karl Moser

Anatase TiO2 is among the most studied materials for light-energy conversion applications, but the nature of its fundamental charge excitations is still unknown. Yet it is crucial to establish whether light absorption creates uncorrelated electron-hole pairs or bound excitons and, in the latter case, to determine their character. Here, by combining steady-state angle-resolved photoemission spectroscopy and spectroscopic ellipsometry with state-of-the-art ab initio calculations, we demonstrate that the direct optical gap of single crystals is dominated by a strongly bound exciton rising over the continuum of indirect interband transitions. This exciton possesses an intermediate character between the Wannier-Mott and Frenkel regimes and displays a peculiar two-dimensional wavefunction in the three-dimensional lattice. The nature of the higher-energy excitations is also identified. The universal validity of our results is confirmed up to room temperature by observing the same elementary excitations in defect-rich samples (doped single crystals and nanoparticles) via ultrafast two-dimensional deep-ultraviolet spectroscopy.

Nature Publishing Group2017

Probing Entangled States of the Nuclear-Electronic Quantum Magnet LiHoF₄

Ivan Kovacevic

EPFL2016