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In this thesis, I present an experimental molecular beam surface scattering study of dynamical processes involved when HCl molecules are scattered from Au(111) and Ag(111) surfaces. I investigated vibrational excitation, translational inelasticity and diss ...
Halogenated organic compounds (so-called organohalides) represent one of the major widespread groundwater pollutants. Organohalide respiration (OHR) is a bacterial anaerobic process in which chlorinated compound, e.g. tetrachloroethene (PCE), is used as te ...
The crystal structure of [ZnCl2(NH3)2], diamminedichloridozinc, was re-investigated at low temperature, revealing the positions of the hydrogen atoms and thus a deeper insight into the hydrogen-bonding scheme in the crystal packing. In comparison with pr ...
We introduce a simple strategy to access and readout nuclear singlet order based on the alternate repetition of hard pulses and delays. We demonstrate the general applicability of the method by accessing nuclear singlet order in spin systems characterized ...
Chlorine dioxide (ClO2) is commonly used as an alternative disinfectant to chlorine in drinking water treatment because it produces limited concentrations of halogenated organic disinfection byproducts. During drinking water treatment, the primary ClO2 byp ...
Bench-scale chloramination under uniform formation conditions was used to examine N-nitrosodimethylamine (NDMA) formation in settled and (bio)filtered drinking water and treated wastewater. In this study, water temperature, pH, postchloramination time, and ...
The discovery of new homogeneous catalysts that preferentially form one product over another in regio- or enantioselective chemical reactions has traditionally been the province of experimental chemists. Today, computational-based approaches have carved an ...
Oxidation processes are impacted by the type, concentration and reactivity of the dissolved organic matter (DOM). In this study, the reactions between various types of DOM (Suwannee River fulvic acid (SRFA), Nordic Reservoir NOM (NNOM) and Pony Lake fulvic ...
Predicting the fate of chloroethenes in groundwater is essential when evaluating remediation strategies. Such predictions are expected to be more accurate when incorporating isotopic parameters. Although secondary chlorine isotope effects have been observe ...
The susceptibility of waterborne viruses to disinfection is known to vary between viruses and even between closely related strains, yet the extent of this variation is not known. Here, different enteroviruses (six strains of coxsackievirus B5, two strains ...
