Publications associées à Cristallisation fractionnée (chimie)

The molecular scale mechanism of deposition ice nucleation on silver iodide

Athanasios Nenes, Mária Lbadaoui-Darvas, André Welti

Heterogeneous ice nucleation is a ubiquitous process in the natural and built environment. Deposition ice nucleation, i.e. heterogeneous ice nucleation that - according to the traditional view - occurs in a subsaturated water vapor environment and in the a ...

Royal Soc Chemistry2024

Crossing the ballistic-ohmic transition via high energy electron irradiation

Philip Johannes Walter Moll, Matthias Carsten Putzke, Maja Deborah Bachmann

The delafossite metal PtCoO2 is among the highest-purity materials known, with low-temperature mean free path up to 5 mu m in the best as-grown single crystals. It exhibits a strongly faceted, nearly hexagonal Fermi surface. This property has profound cons ...

AMER PHYSICAL SOC2023

Three-dimensional in situ imaging of single-grain growth in polycrystalline In2O3:Zr films

Quentin Thomas Jeangros, Monica Morales Masis, Michael Elias Stückelberger

Understanding grain morphology and kinetics of solid-phase crystallization is important for controlling the functional properties of polycrystalline materials. Here, in situ coherent X-ray diffraction imaging and transmission electron microscopy elucidate ...

SPRINGERNATURE2022

Bifunctional additive 2-amino-3-hydroxypyridine for stable and high-efficiency tin-lead perovskite solar cells

Mohammad Khaja Nazeeruddin, Yi Zhang, Bing Zhang, Keith Gregory Brooks

Tin-lead (Sn-Pb) mixed perovskite has received widespread attention due to its suitable band gap width and high optical absorption coefficients. However, the power conversion efficiency (PCE) of Sn-Pb mixed perovskite solar cells (PSCs) is still low due to ...

Royal Society of Chemistry2022

A combined molecular dynamics and experimental study of two-step process enabling low-temperature formation of phase-pure α-FAPbI3

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Paramvir Ahlawat, Essa Awadh R Alharbi, Haizhou Lu

It is well established that the lack of understanding the crystallization process in a two-step sequential deposition has a direct impact on efficiency, stability, and reproducibility of perovskite solar cells. Here, we try to understand the solid-solid ph ...

2021

Structural properties of organometalic halide perovskite and their application in photodetectors

Anastasiia Glushkova

Hybrid organometallic halide perovskites have been intensively investigated in the past years as highly efficient light harvesters for various optoelectronic applications for both sensing and emitting light. However, many open questions remain regarding th ...

EPFL2020

Entropy as a tool for crystal discovery

Pablo Miguel Piaggi

The computational prediction of crystal structures has emerged as an useful alternative to expensive and often cumbersome experiments. We propose an approach to the prediction of crystal structures and polymorphism based on reproducing the crystallization ...

EPFL2019

Predicting polymorphism in molecular crystals using orientational entropy

Pablo Miguel Piaggi, Michele Parrinello

We introduce a computational method to discover polymorphs in molecular crystals at finite temperature. The method is based on reproducing the crystallization process starting from the liquid and letting the system discover the relevant polymorphs. This id ...

National Academy of Sciences2018

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes

Kumar Varoon Agrawal, Guangwei He, Deepu Joseph Babu

We report the synthesis of thin, highly intergrown, polycrystalline metal-organic framework (MOF) membranes on a wide range of unmodified porous and non-porous supports (polymer, ceramic, metal, carbon, and graphene). We developed a novel crystallization t ...

JOURNAL OF VISUALIZED EXPERIMENTS2018

From 2D to 3D Characterization of Materials Subjected to Extreme Pressure and Temperature Conditions

Farhang Nabiei

Planetesimal were the first planetary objects to form in the solar system, which later grew to make the proto-planets. Most of these bodies were differentiated as a result of internal heating. Several differentiated bodies have, then, been accreted followi ...

EPFL2017