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The high hydrogen content in complex hydrides such as M[AIH 4]x and M[BH4]x (M = Li, Na, K, Mg, Ca) stimulated many research activities to utilize them as hydrogen storage materials. An understanding of the dynamical properties on the molecular level is im ...
Since the beginning of the twenty-first century the limitations of the fossil age with regard to the continuing growth of energy demand, the peaking mining rate of oil, the growing impact of CO2 emissions on the environment and the dependency of the econom ...
A series of thiolate gold(I) derivatives bearing water soluble phosphanes - namely sodium triphenylphosphane monosulfonate (TPPMS), sodium triphenylphosphane trisulfonate (TPPTS), 1,3,5-triaza-7-phosphaadamantane (PTA) and 3,7-diacetyl-1,3,7-triaza-5-phosp ...
The widespread adoption of hydrogen as an energy carrier could bring significant benefits, but only if a number of currently intractable problems can be overcome. Not the least of these is the problem of storage, particularly when aimed at use onboard ligh ...
Aluminium (Al 99.99 % purity) and aluminium alloy Al-5.7Ni and Al-5Mg (wt.%) open-cell foams made by replication processing are creep-tested in the temperature range T/Tm=0.5-0.8, varying the relative density between 0.10 and 0.25. Steady state creep rates ...
The thermal decomposition of alane was investigated by application of synchrotron X-ray diffraction (SR-XRD) and thermal desorption spectroscopy (TDS). Two polymorphs were studied, α- and γ-AlH3. Activation energies, anisotropic volume expansions, and phas ...
Cobalt complexes supported by diglyoxime ligands of the type Co(dmgBF2)2(CH3CN)2 and Co(dpgBF2)2(CH3CN)2 (where dmgBF2 is difluoroboryl-dimethylglyoxime and dpgBF2 is difluoroboryl-diphenylglyoxime), as well as cobalt complexes with [14]-tetraene-N4 (Tim) ...
The water soluble ruthenium(II) complex [RuCl2(PTA)([9]aneS3)] (PTA = 1,3,5-triaza-7-phosphadamantane, [9]aneS3 = 1,4,7-trithiacyclononane) catalyzes the hydrogenation of CO2 and bicarbonate in aqueous solution. ...
Bis-phosphine Ru(II)-arene complexes are highly active and chemoselective catalysts for the hydrogenation of aldehydes in the presence of olefinic bonds. Mechanistic studies, including comparisons with a structural analog, reactions of an isolated hydride ...
The ruthenium(II)-triphos acetato complex [RuCl(OAc)(k3-triphos)] (triphos = (PPh2CH2)3CMe) has been found to be an active catalyst precursor for the hydrogenation of 1-alkenes under relatively mild conditions (5-50 bar H2, 50 °C). In contrast to related t ...
