Concept

Cycle carbone-azote-oxygène

Publications associées (35)

Unified Strategy to Monoterpene Indole Alkaloids: Total Syntheses of (±)-Goniomitine, (±)-1,2-Dehydroaspidospermidine, (±)-Aspidospermidine, (±)-Vincadifformine, and (±)-Kopsihainanine A

Qian Wang, Jieping Zhu, Zhengren Xu, Olivier Wagnières

Total syntheses of (±)-goniomitine, (±)-1,2-dehydroaspidospermidine, (±)-aspidospermidine, (±)-vincadifformine, and (±)-kopsihainanine A were achieved featuring two common key steps: (1) a palladium-catalyzed decarboxylative vinylation that provides quick ...

Amer Chemical Soc2014

Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-Biaryl Sulfonated Phosphines in Aqueous Solution

Gabor Laurenczy, Katerina Stefania Sordakis

The selective dehydrogenation of aqueous solutions of HCOOH/HCOONa to H2 and CO2 gas mixtures has been investigated using RuCl3·3H2O as a homogeneous catalyst precursor in the presence of di␣erent monoaryl-biaryl or alkyl-biaryl phosphines and aryl diphosp ...

American Chemical Society2014

Ultrathin Cobalt-Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst

Xile Hu, Fang Song

Cost-effective production of solar fuels requires robust and earth-abundant oxygen evolution reaction (OER) catalysts. Herein, we report that ultrathin nanoplates of cobaltmanganese layered double hydroxide (CoMn LDH) are a highly active and stable oxygen ...

American Chemical Society2014

Kinetics and Mechanism of Formic Acid Decomposition in Aqueous Solution using Ruthenium Pre-catalysts with Hydrophilic Phosphine Ligands

Weijia Gan

Hydrogen holds the potential to be an alternative to replace fossil fuels in the future. The tremendous research effort dedicated to the issue of hydrogen storage has led to considerable advancements in the development of both adsorption materials and chem ...

EPFL2012

Uniform broadband excitation of crystallites in rotating solids using interleaved sequences of delays alternating with nutation

Geoffrey Bodenhausen, Simone Ulzega, Marc Anthony Caporini

In solids that are spinning about the magic angle, trains of short pulses in the manner of Delays Alternating with Nutations for Tailored Excitation (DANTE) allow one to improve the efficiency of the excitation of magnetization compared to rectangular puls ...

Elsevier2012

The transverse relaxation rates R (2) = 1/T (2) of protons can be determined by spin-echo sequences with multiple refocusing pulses using moderate radio-frequency field strengths and properly chosen inter-pulse delays so as to suppress echo modulations due ...

Springer Vienna2012

Evidence for a new path to the self-sustainment of the thermonuclear fusion in magnetically confined burning plasma experiments

Duccio Testa, Mattia Albergante

In this work we provide the first explanation for observations made in 1997 on the Joint European Torus of unexpected ion heating with fusion-born alpha particles occurring over time scales much shorter than those theoretically foreseen. We demonstrate tha ...

2012

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A train of short rotor-synchronized pulses in the manner of Delays Alternating with Nutations for Tailored Excitation (DANTE) applied to nitrogen-14 nuclei (I = 1) in samples spinning at the magic angle at high frequencies (typically nu(rot) = 62.5 kHz so ...

Elsevier2011

Effects of short-term ecosystem experimental warming on water-extractable organic matter in an ombrotrophic Sphagnum peatland (Le Forbonnet, France)

Alexandre Buttler, Vincent Eric Jules Jassey

In a future warmer world, peatlands may change from a carbon sink function to a carbon source function. This study tracks changes in water-extractable organic matter (WEOM) after 1 year of in situ experimental warming using open top chambers (OTCs). WEOM w ...

2011

Modelling of microturbulence-driven transport of energetic ions in an ITER steady-state scenario is presented. Results indicate that a significant fraction of the velocity space distribution of alpha particles and deuterium ions can be transported above ne ...

International Atomic Energy Agency2010

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