Concept

Dodécacarbonyle de trifer

Publications associées (16)

The Pristine survey VI. The first three years of medium-resolution follow-up spectroscopy of Pristine EMP star candidates

Nicolas Lawrence Etienne Longeard, Carmela Lardo, Romain Ely Roland Lucchesi

We present the results of a 3-yr long, medium-resolution spectroscopic campaign aimed at identifying very metal -poor stars from candidates selected with the CaHK, metallicitysensitive Pristine survey. The catalogue consists of a total of 1007 stars, and i ...

OXFORD UNIV PRESS2019

An In Situ Surface-Enhanced Infrared Absorption Spectroscopy Study of Electrochemical CO2 Reduction: Selectivity Dependence on Surface C-Bound and O-Bound Reaction Intermediates

Nicola Marzari, Oliviero Andreussi, Francesco Nattino

The CO2 electroreduction reaction (CO2RR) is a promising avenue to convert greenhouse gases into high-value fuels and chemicals, in addition to being an attractive method for storing intermittent renewable energy. Although polycrystalline Cu surfaces have ...

AMER CHEMICAL SOC2019

The effect of iron binding on uranyl(V) stability

Rosario Scopelliti, Marinella Mazzanti, Radmila Faizova

Here we report the effect of UO2+⋯Fe2+ cation–cation interactions on the redox properties of uranyl(V) complexes and on their stability with respect to proton induced disproportionation. The tripodal heptadentate Schiff base trensal3− ligand allowed the sy ...

2018

Remarkable enhancement of bacterial inactivation in wastewater through promotion of solar photo-Fenton at near-neutral pH by natural organic acids

César Pulgarin, Stefanos Giannakis, Paola Villegas Guzman

In this work, the near-neutral photo-Fenton process, as a means of wastewater disinfection, was enhanced by the addition of Organic Acids (OAs), namely citric, ascorbic, tartaric and caffeic acid. The addition of OAs exhibited significant bacterial inactiv ...

Elsevier2017

Iohexol degradation in wastewater and urine by UV-based Advanced Oxidation Processes (AOPs): Process modeling and by-products identification

Hubert Girault, César Pulgarin, Natalia Gasilova, Stefanos Giannakis, Milica Jovic, Simon Schindelholz, Miquel Pastor Gelabert

In this work, an Iodinated Contrast Medium (ICM), Iohexol, was subjected to treatment by 3 Advanced Oxidation Processes (AOPs) (UV, UV/H2O2, UV/H2O2/Fe2+). Water, wastewater and urine were spiked with Iohexol, in order to investigate the treatment efficien ...

Elsevier2017

Building Composite Iron-Manganese Oxide Flowerlike Nanostructures: A Detailed Magnetic Study

Davide Deiana

Here we show that it is possible to produce different magnetic core multiple shell heterostructures from monodisperse Fe3O4 spherical magnetic seeds by finely controlling the amount of a manganese precursor and using, in a smart and simple way, a cation-ex ...

Amer Chemical Soc2017

Iron Complexes for Hydrogen Activation and Catalytic Hydrogenation

Simona Mazza

Inspired by Nature several groups have developed structural and functional iron complexes mimicking the active site of the iron-hydrogenases, which show high reactivity in the H2 cleavage. Usually pendant bases have been incorporated onto families of Fe co ...

EPFL2015

Ligand Coupling Symmetry Correlates with Thermopower Enhancement in Small-Molecule/Nanocrystal Hybrid Materials

Wendy Lee Queen, Michele Kotiuga

The authors study the impact of the coupling symmetry and chem. nature of org.-inorg. interfaces on thermoelec. transport in Cu2-xSe nanocrystal thin films. By coupling ligand-exchange techniques with layer-by-layer assembly methods, the authors are able t ...

2014

Reaction of Ferrate(VI) with ABTS and Self-Decay of Ferrate(VI): Kinetics and Mechanisms

Urs von Gunten, Yun Ho Lee

Reactions of ferrate(VI) during water treatment generate perferryl(V) or ferryl(IV) as primary intermediates. To better understand the fate of perferryl(V) or ferryl(IV) during ferrate(VI) oxidation, this study investigates the kinetics, products, and mech ...

Amer Chemical Soc2014

Time-Resolved X-Ray Microtomography Observation of Intermetallic Formation Between Solid Fe and Liquid Al

Michel Rappaz, Cécile Hébert, Aïcha Hessler-Wyser, Guillaume Pasche

Time-resolved in situ X-ray tomography combined with scanning electron microscopy was performed on an Al-Fe diffusion system at 973 K (700 A degrees C) to study the formation of the main intermetallic compounds occurring at the interface. After nucleation ...

Springer US2013

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