Publications associées à Réaction réversible

Grand canonical Brownian dynamics simulations of adsorption and self-assembly of SAS-6 rings on a surface

The Spindle Assembly Abnormal Protein 6 (SAS-6) forms dimers, which then self-assemble into rings that are critical for the nine-fold symmetry of the centriole organelle. It has recently been shown experimentally that the self-assembly of SAS-6 rings is st ...

AIP Publishing2023

Non-equilibrium kinetics and trajectory thermodynamics of synthetic molecular pumps

Cristian Pezzato

A major goal in the design of synthetic molecular machines is the creation of pumps that can use the input of energy to transport material from a reservoir at low chemical potential to a different reservoir at higher chemical potential, thereby forming and ...

ROYAL SOC CHEMISTRY2020

Structure and reactivity of the polarised liquid–liquid interface: what we know and what we do not

Hubert Girault, Astrid Johana Olaya Avendano, Pekka Eero Peljo, Grégoire Clément Gschwend

Charge transfer phenomena at the interface between two immiscible electrolyte solutions (ITIES) are electrochemical reactions taking place in soft media. Owing to their liquid nature, the ITIES shows a large panel of electrochemical reactions including ele ...

2020

System and method for ground consolidation

Lyesse Laloui, Dimitrios Terzis, Patrick Gabriel Yihsiu-Ming Hicher

The present invention relates to a method for inducing ground consolidation. The method comprises providing a first chamber (7) in a first hole (3) in the ground (5), and a second chamber (7) in a second hole (3) in the ground (5), the first and second cha ...

2020

Uncertainty propagation for the design study of the PETALE experimental programme in the CROCUS reactor

Andreas Pautz, Vincent Pierre Lamirand, Axel Guy Marie Laureau, Dimitri Rochman

The PETALE experimental programme in the CROCUS reactor intends to provide integral measurements to constrain stainless steel nuclear data. This article presents the tools and the methodology developed to design and optimize the experiments, and its operat ...

2020

Stronger Reductive Environment in Solvothermal Synthesis Leads to Improved Ga Doping Efficiency in ZnO Nanocrystals and Enhanced Plasmonic Absorption

Reinis Ignatans

The key parameter for degenerated semiconductor oxide plasmonic nanocrystals is the doping level. Hydrothermal and solvothermal approaches are considered to be less effective toward achieving high concentration of aliovalent donor dopants in a host oxide w ...

Wiley-VCH Verlag2019

Nanosecond electron pulses in the analytical electron microscopy of a fast irreversible chemical reaction

Thomas La Grange

We show how the kinetics of a fast and irreversible chemical reaction in a nanocrystalline material at high temperature can be studied using nanosecond electron pulses in an electron microscope. Infrared laser pulses first heat a nanocrystalline oxide laye ...

Springer2019

Photocatalytic Performance of CuxO/TiO2 Deposited by HiPIMS on Polyester under Visible Light LEDs: Oxidants, Ions Effect, and Reactive Oxygen Species Investigation

Sami Rtimi

In the present study, we propose a new photocatalytic interface prepared by high-power impulse magnetron sputtering (HiPIMS), and investigated for the degradation of Reactive Green 12 (RG12) as target contaminant under visible light light-emitting diodes ( ...

2019

Semiclassical analysis of the quantum instanton approximation

Jiri Vanicek, Christophe Louis Joseph Jean-Luc Vaillant

We explore the relation between the quantum and semiclassical instanton approximations for the reaction rate constant. From the quantum instanton expression, we analyze the contributions to the rate constant in terms of minimum-action paths and find that t ...

2019

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone

Here we show that a scaffold combining siloxide ligands and a bridging oxide allows the synthesis and characterization of the stable dinuclear uranium(IV) hydride complex [K-2{U(OSi((OBu)-Bu-t)(3))(3)(mu-O)(mu-H)(2)}], 2, which displays high reductive ...

2019