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A systematic study of the mass spectra of particles formed in a supersonic nozzle expansion of Zn, Cd, and Hg vapors together with Na was performed. The particles discussed in this paper contain only 1 heavy atom and
Hexavalent chromium, Cr(VI), can be immobilized under neutral to alkaline conditions by reduction to Cr(III); similarly, the mobility of naturally occurring Cr in soils and sediments can be limited by its occurrence in the +III oxidation state. Conversely, ...
A review. In an effort to develop new tripodal N-heterocyclic carbene (NHC) ligands for small mol. activation, two new classes of tripodal NHC ligands TIMER and TIMENR were synthesized. The C-anchored tris(carbene) ligand system TIMER (R = Me, t-Bu) forms ...
This review commences with a survey of the general synthetic routes leading to aminophosphines containing the P-NH subgroup. Recent examples involving functionalised and chiral aminophosphines are included. The synthesis and structural properties of deprot ...