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Publications associées (124)
Redox Properties of Flavin in BLUF and LOV Photoreceptor Proteins from Hybrid QM/MM Molecular Dynamics Simulation
Flavins play an important role in many oxidation and reduction processes in biological systems. For example, flavin adenine dinucleotide (FAD) and flavin mononucleotide (FMN) are common cofactors found in enzymatic proteins that use the special redox prope ...
Amer Chemical Soc2024Realization of Organocerium-Based Fullerene Molecular Materials Showing Mott Insulator-Type Behavior
Electron-rich organocerium complexes (C5Me4H)(3)Ce and [(C5Me5)(2)Ce(ortho-oxa)], with redox potentials E-1/2 = -0.82 V and E-1/2 = -0.86 V versus Fc/Fc(+), respectively, were reacted with fullerene (C-60) in different stoichiometries to obtain molecular m ...
Amer Chemical Soc2024Microstructure - Electrochemical Surface Reactivity Relationship of Electrochemically Grown Manganese Oxides Films
This Thesis provides a comprehensive and correlative investigation of the microstructure, chemical state, and electrochemical reactivity of manganese oxide (MnOx) films, aiming to gain a deeper understanding of the deposition and dissolution mechanism of M ...
EPFL2024Unraveling the Effect of the Chemical and Structural Composition of ZnxNi1-xFe2O4 on the Electron Transfer at the Electrochemical Interface
Sandro Carrara, Mallikarjun Madagalam
In order to deepen the understanding of the role of transition metal oxides in electron transfer at the electrochemical interface, the performance of ZnxNi1-xFe2O4 (x = 0, 0.2, 0.4, 0.6, 0.8, 1) nanomaterials in electrochemical sensing is studied. Nanomate ...
WILEY2023Effect of a temperature gradient on the screening properties of ionic fluids
Federico Grasselli, Andrea Grisafi
The electrostatic screening properties of ionic fluids are of paramount importance in countless physical processes. Yet the screening behavior of ionic conductors out of thermal equilibrium has to date mainly been studied in the context of thermoelectric p ...
AMER PHYSICAL SOC2023A locally activatable sensor for robust quantification of organellar glutathione
Pablo Rivera Fuentes, Sarah Emmert, Gianluca Quargnali
Glutathione (GSH) is the main determinant of intracellular redox potential and participates in multiple cellular signalling pathways. Achieving a detailed understanding of intracellular GSH homeostasis depends on the development of tools to map GSH compart ...
NATURE PORTFOLIO2023Investigating the bioaccumulation potential of anionic organic compounds using a permanent rainbow trout liver cell line
Kristin Schirmer, Juliane Hollender, Fabian Gerhard Peter Balk
Permanent rainbow trout (Oncorhynchus mykiss) cell lines represent potential in vitro alternatives to experiments with fish. We here developed a method to assess the bioaccumulation potential of anionic organic compounds in fish, using the rainbow trout li ...
PERGAMON-ELSEVIER SCIENCE LTD2023High-Stable Lead-Free Solar Cells Achieved by Surface Reconstruction of Quasi-2D Tin-Based Perovskites
Michael Saliba, Antonio Abate, Feng Yang, Guixiang Li, Meng Li, Xingyu Gao, Rui Zhu, Zhe Li
Tin halide perovskites are an appealing alternative to lead perovskites. However, owing to the lower redox potential of Sn(II)/Sn(IV), particularly under the presence of oxygen and water, the accumulation of Sn(IV) at the surface layer will negatively impa ...
Weinheim2023Mechanical Properties of FRP Materials at Elevated Temperature. Definition of a Temperature Conversion Factor for Design in Service Conditions
Thomas Keller, Mário Alexandre De Jesus Garrido
One of the main concerns about the use of fibre reinforced polymer (FRP) materials in civil engineering structural applications is the potential reduction of their stiffness- and strength-related properties when exposed to elevated temperature. The first p ...
SPRINGER-VERLAG SINGAPORE PTE LTD2022Bottom-Pressure Development Due to an Abrupt Slope Reduction at Stepped Spillways
Anton Schleiss, Michael Pfister, José Pedro Gamito de Saldanha Calado Matos, Mohammad Javad Ostad Mirza
Fluctuating bottom-pressures on stepped chutes are relevant for the spillway design. An abrupt slope reduction causes a local alteration of the bottom-pressure development. Little information is available regarding the air–water flow properties near an abr ...
2022