Résumé
In chemistry, a regular solution is a solution whose entropy of mixing is equal to that of an ideal solution with the same composition, but is non-ideal due to a nonzero enthalpy of mixing. Such a solution is formed by random mixing of components of similar molar volume and without strong specific interactions, and its behavior diverges from that of an ideal solution by showing phase separation at intermediate compositions and temperatures (a miscibility gap). Its entropy of mixing is equal to that of an ideal solution with the same composition, due to random mixing without strong specific interactions. For two components where is the gas constant, the total number of moles, and the mole fraction of each component. Only the enthalpy of mixing is non-zero, unlike for an ideal solution, while the volume of the solution equals the sum of volumes of components. A regular solution can also be described by Raoult's law modified with a Margules function with only one parameter : where the Margules function is Notice that the Margules function for each component contains the mole fraction of the other component. It can also be shown using the Gibbs-Duhem relation that if the first Margules expression holds, then the other one must have the same shape. A regular solutions internal energy will vary during mixing or during process. The value of can be interpreted as W/RT, where W = 2U12 - U11 - U22 represents the difference in interaction energy between like and unlike neighbors. In contrast to ideal solutions, regular solutions do possess a non-zero enthalpy of mixing, due to the W term. If the unlike interactions are more unfavorable than the like ones, we get competition between an entropy of mixing term that produces a minimum in the Gibbs free energy at x1 = 0.5 and the enthalpy term that has a maximum there. At high temperatures, the entropic term in the free energy of mixing dominates and the system is fully miscible, but at lower temperatures the G(x1) curve will have two minima and a maximum in between.
À propos de ce résultat
Cette page est générée automatiquement et peut contenir des informations qui ne sont pas correctes, complètes, à jour ou pertinentes par rapport à votre recherche. Il en va de même pour toutes les autres pages de ce site. Veillez à vérifier les informations auprès des sources officielles de l'EPFL.
Cours associés (3)
ChE-403: Heterogeneous reaction engineering
The theoretical background and practical aspects of heterogeneous reactions including the basic knowledge of heterogeneous catalysis are introduced. The fundamentals are given to allow the design of m
CH-160(b): General chemistry
Cet enseignement vise l'acquisition des notions essentielles relatives à la structure de la matière, aux équilibres et à la réactivité chimiques. Le cours et les exercices fournissent la méthodologie
MSE-422: Advanced metallurgy
This course covers the metallurgy, processing and properties of modern high-performance metals and alloys (e.g. advanced steels, Ni-base, Ti-base, High Entropy Alloys etc.). In addition, the principle