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2-Methylprop-2-ene-, prop-2-ene-, 1-methylprop-2-ene-, and (E)-but-2-enesulfonyl chlorides have been used as electrophilic partners in desulfinylative palladium- catalyzed C–C coupling with Grignard reagents and sodium salts of dimethyl malonate and methyl ...
Tuning of effective band gaps at insulator surfaces by adsorbed molecules is of fundamental interest but also technologically relevant for contact charging induced by adsorbed molecules like hydroxybenzoic acids. Our studies by density functional theory of ...
Two different fluorescent single walled carbon nanotubes (SWNT) were prepd. First by a reaction of oxidized SWNT-K salt with 1,3-bis(9-anthracenylmethyl)imidazolium chloride (bamim)Cl to provide a fluorescent system SWNT-(bamim), via ion exchange and forma ...
The HOCl heterogeneous reaction on frozen natural (NSS) and recrystallized (RSS) sea salt KCl and NaCl solutions was studied using a low pressure flow reactor in order to measure the uptake coefficient gamma and products of reaction The HOCl sample used in ...
Oldenbourg Wissenschaftsverlag GmbH, De Gruyter2010
The structure of ultrathin NaCl films on Au(1 1 1) and on Au(11 12 12), as well as the one of bimolecular 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) and 1,4-bis-(2,4-diamino-1,3,5,-triazine)-benzene (BDATB) islands on NaCl films on both surfaces have ...
This article presents a comprehensive modeling of temperature, carbonation, water and chloride ions transport in cover concrete using the transport model "TransChlor". The TransChlor transport model employs weather data and chloride ion concentrations pres ...
In recent years, new types of water contaminants have emerged. More and more focus is notably set on pharmaceuticals, personal care products or pesticides, as it has been observed that these substances are commonly found in surface water. This contaminatio ...
Chloride ion is in part bound into ordinary Portland cement paste and modifies its mineralogy. To understand this a literature review of its impacts has been made and new experimental data were obtained. Phase pure preparations of Friedel's salt, Ca4Al2(Cl ...
Benzo-15-crown-5 functionalized polymer brushes prepared via surface-initiated atom transfer radical polymerization are used as the active layer in a potassium-selective quartz crystal microbalance sensor. The polymer brushes allow the selective detection ...
Results of the single molecule force spectroscopy study of specific interactions between ribonuclease barnase and its inhibitor barstar are presented. Experimental data obtained for the force loading rate ranging 2-70 nN/s are well approximated by a single ...