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Metal-organic frameworks (MOFs), a class of porous materials, are of particular interest in gas storage and separation applications due largely to their high internal surface areas and tunable structures. MOF-5 is perhaps the archetypal MOF; in particular, ...
Methane (CH4) is an important greenhouse gas, second only to CO2, and is emitted into the atmosphere at different concentrations from a variety of sources. However, unlike CO2, which has a quadrupole moment and can be captured both physically and chemicall ...
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We have conducted large-scale screening of zeolite materials for CO 2/CH4 and CO2/N2 membrane separation applications using the free energy landscape of the guest molecules inside these porous materials. We show how advanced molecular simulations can be in ...
The pores in cementitious materials, their sizes and connectivity have an important influence on the durability of concrete. Several microstructural models have been developed to simulate the three-dimensional pore network in cement pastes. In this article ...
Microcellular aluminium can be produced by replication in porous material with pores across a wide range of sizes but with otherwise identical structures. Compressive tests reveal a plasticity size effect, with samples showing higher strengths and higher r ...
Adsorption of mols. in functionalized and high surface area microporous materials is of technol. importance in a multitude of areas ranging from catalysis,1 drug delivery,2 chem. sepns.3 and energy storage4 to personal care products5. Over the past several ...
Methane can be an alternative fuel for vehicular usage provided that new porous materials are developed for its efficient adsorption-based storage. Herein, we search for materials for this application within the family of diamond analogues. We used density ...
The favorable and adjustable transport properties of porous media make them suitable components in reactors used for solar energy conversion and storage processes. The directed engineering of the porous media's morphology can significantly improve the perf ...
We explore selected aspects of J.-Y. Parlange’s contributions to hydrological transport of solutes and sediments, including both the laboratory and field scales. At the laboratory scale, he provided numerous approximations for solute transport accounting f ...
Effects of Mn redox cycling on the stability of bioreduced U(IV) are evaluated here. U(VI) can be biologically reduced to less soluble U(IV) species and the stimulation of biological activity to that end is a salient remediation strategy; however, the stab ...