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In 1902, a contributor to Popular Science affirmed that “The era of the amateur scientist is passing; science must now be advanced by the professional expert.” Throughout the twentieth century, amateurs have been increasingly excluded from the production o ...
Many scientific inquiries in natural sciences involve approximating a spherical field –namely a scalar quantity defined over a continuum of directions– from generalised samples of the latter. Typically, a convex optimisation problem is formulated in terms ...
Understanding planetary atmosphere-surface exchange and extra-terrestrial-surface formation processes within our Solar System is one of the fundamental goals of planetary science research. There has been a revolution in planetary surface observations over ...
The palladium-catalyzed reaction of a-haloketones with isocyanides afforded -oxo-ketenimines through alpha-hydride elimination of the beta-oxo-imidoyl palladium intermediates. Reaction of these relatively stable alpha-oxo ketenimines with nucleophiles suc ...
The search for technosignatures from hypothetical galactic civilizations is going through a new phase of intense activity. For the first time, a significant fraction of the vast search space is expected to be sampled in the foreseeable future, potentially ...
The lack of evidence for the existence of extraterrestrial life, even the simplest forms of animal life, makes it is difficult to decide whether the search for extraterrestrial intelligence (SETI) is more a high-risk, high-payoff endeavor than a futile att ...
As part of the understanding of radiative coupling phenomena with ablation phenom- ena for hypersonic re-entry of Hayabusa or Stardust type of capsules, laboratory tests are very important. Only expansion tubes can reproduce flight conditions at these spee ...
The reaction of allyl ethyl carbonates with isocyanides in the presence of a catalytic amount of Pd(OAc)2 provided ketenimines through b-hydride elimination of the allyl imidoylpalladium intermediates. The insertion of the isocyanide into the p-allyl Pd co ...
The existence of life in extreme conditions, in particular in extraterrestrial environments, is certainly one of the most intriguing scientific questions of our time. In this report, we demonstrate the use of an innovative nanoscale motion sensor in life-s ...
In the first chapter of this thesis, the development of two new reactions for the synthesis of vinyl ketenimines and alpha-oxo-ketenimines from isocyanides is presented. These palladium-catalyzed transformations both feature an isocyanide insertion / beta- ...