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The 2J (13C, H), a measure of bond angle in CH2:CHCH2R (R = MgBr, Li, Na, K), (Z)- and (E)-MeCH:CHCH2K, CH2:CHCH:CHCH2R (R = Li, K), or (E)-hexadienyllithium, is used to assign the % s character in the C-H bonds. This and the 13C NMR chem. shifts indicate ...
Interaction of V2O5 with TiO2 during prepn. of V/Ti-oxide catalysts via solid-state reaction was studied using in situ FT-Raman spectroscopy, HRTEM and XPS. This interaction results in the formation of monomeric vanadia species with vanadium in tetrahedral ...
We review, from a unified point of view, a general class of models of itinerant electrons interacting with classical fields. Applications to the static Holstein, Kondo, and Hubbard models are discussed. The ground state structure of the classical field is ...
When electrons are subject to a potential with two incommensurate periods, translational invariance is lost, and no periodic band structure is expected. However, model calculations based on nearly free one-dimensional electrons and experimental results fro ...
Quenching of the exciton luminescence of GaN epitaxial films and GaN/AlGaN quantum wells in an electric field is observed and attributed to impact ionization of excitonic states by hot electrons. It is found that impurity scattering rules the momentum rela ...
The present invention relates to a new family of mono, bis or tris (2,2'-substituted bipyridine) complexes of a metal selected amongst iron, ruthenium, osmium or vanadium, the bipyridine being substituted by at least one electron donor group. According to ...
The aim of the invention is to improve existing amperometric sensors used to measure the quantity of a component present in a solution. This aim is reached by using a sensor provided with a measuring electrode (20) having at least one current collector (37 ...
A simple method is presented which allows to est. the facility of the electrochem. oxidn. of org. species using the electrochem. oxidizability index (EOI) and the degree of oxidn. using the electrochem. oxygen demand (EOD). At platinum anode only benzene d ...
