Christos Comninellis

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Publications associées (93)

Investigation of the "permanent" electrochemical promotion of catalysis (P-EPOC) by electrochemical mass spectrometry (EMS) measurements

Christos Comninellis, Cyril Falgairette, Chun Xia

The phenomenon of electrochemical promotion of catalysis (EPOC) is most often fully reversible. Subsequent to long-lasting polarization, however, the new steady-state open-circuit catalytic activity after current interruption may remain significantly highe ...

Elsevier2010

Investigation of the Pt/YSZ interface at low oxygen partial pressure by solid electrochemical mass spectroscopy under high vacuum conditions

Christos Comninellis, Wolfgang Harbich, György Foti, Cyril Falgairette, Chun Xia

The Pt/YSZ interface was investigated at low oxygen partial pressure under high vacuum (HV) conditions at 400 A degrees C. Two different electrochemical techniques were coupled to mass spectrometric gas analysis using a new solid electrochemical mass spect ...

Springer Netherlands2010

Microelectrode-array of IrO2 prepared by thermal treatment of pure Ir

Christos Comninellis, Agnieszka Kapalka, Stéphane Fierro, Olivier Frey

In this paper, the IrO2 electrode preparation technique consisting in thermal treatment of pure Ir in air was used in order to produce an IrO2-based microelectrode-array (TOIROF-MEA) with low capacitive background current. The TOIROF-MEA was characterized ...

Elsevier2010

Solid electrochemical mass spectrometry (SEMS) for investigation of supported metal catalysts under high vacuum

Christos Comninellis, Wolfgang Harbich, Cyril Falgairette, Chun Xia

A new experimental set-up, coupling electrochemistry and mass spectroscopic techniques, for the investigation of a solid electrochemical cell under high vacuum conditions (HV) is presented. Two configurations are realized allowing the investigation of both ...

Springer Netherlands2010

Basic principles of the electrochemical mineralization of organic pollutants for wastewater treatment

Christos Comninellis, Agnieszka Kapalka, György Foti

2010

Determination of a scale-up factor from mixing time studies in orbitally shaken bioreactors

Christos Comninellis, Florian Maria Wurm, Mohamed Farhat, David Hacker, Stéphanie Tissot

Efficient mixing in bioreactors is essential in order to avoid concentration gradients which can be harmful for mammalian cells. To study mixing and its scalability in orbitally shaken cylindrical bioreactors, we measured mixing times in containers with no ...

Elsevier2010

Investigation of formic acid oxidation on Ti/IrO2 electrodes

Christos Comninellis, Stéphane Fierro, Lassine Ouattara, Erika Herrera Calderon

2009

Electrochemical comparison between IrO2 prepared by anodic oxidation of pure iridium and IrO2 prepared by thermal decomposition of H2IrC16 precursor solution

Christos Comninellis, Stéphane Fierro, Olivier Frey, Lassine Ouattara

Surface redox activities, oxygen evolution reaction (OER), oxidation of formic acid (FA), and anodic stability were investigated and compared for IrO2 electrodes prepared by two techniques: the thermal decomposition of H2IrCl6 precursor (TDIROF) and the an ...

Springer Netherlands2009

A DEMS study of methanol and formic acid oxidation on boron-doped diamond electrode

Christos Comninellis, Agnieszka Kapalka, György Foti

The electrochemical oxidation of methanol and formic acid in 1 M HClO4 is studied on boron-doped diamond electrode using differential electrochemical mass spectrometry (DEMS). DEMS is used to identify products and intermediates of the reaction monitored on ...

2009

Electrochemical behaviour of ammonia (NH4+/NH3) on electrochemically grown anodic iridium oxide film (AIROF) electrode

Christos Comninellis, Agnieszka Kapalka, Stéphane Fierro, Olivier Frey

The electrochemical behaviour of ammonia (NH4+/NH3) in sodium perchlorate at pH 9 has been investigated on electrochemically grown anodic iridium oxide film (AIROF) electrode. In base electrolyte at pH 9, the Ir(IV)/Ir(III) surface redox couple exhibits un ...

Elsevier2009

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Investigation of the "permanent" electrochemical promotion of catalysis (P-EPOC) by electrochemical mass spectrometry (EMS) measurements

Christos Comninellis, Cyril Falgairette, Chun Xia

Elsevier2010

Investigation of the Pt/YSZ interface at low oxygen partial pressure by solid electrochemical mass spectroscopy under high vacuum conditions

Christos Comninellis, Wolfgang Harbich, György Foti, Cyril Falgairette, Chun Xia

Springer Netherlands2010

Electrochemical comparison between IrO2 prepared by anodic oxidation of pure iridium and IrO2 prepared by thermal decomposition of H2IrC16 precursor solution

Christos Comninellis, Stéphane Fierro, Olivier Frey, Lassine Ouattara

Springer Netherlands2009

Electrochemical behaviour of ammonia (NH4+/NH3) on electrochemically grown anodic iridium oxide film (AIROF) electrode

Christos Comninellis, Agnieszka Kapalka, Stéphane Fierro, Olivier Frey

Elsevier2009