This work is addressing the arenes' hydrogenation-the processes of high importance for petrochemical, chemical and pharmaceutical industries. Noble metal (Pd, Pt, Ru) nanoparticles (NPs) stabilized in hyper-cross-linked polystyrene (HPS) were shown to be a ...
Hydrogenation of aromatic compounds is a widely used catalytic process in modern industry. Selective hydrogenation of benzene (BZ)-toluene (TL) mixtures is an important industrial process as it allows the purification of BZ for further synthetic purposes. ...
Efficient structured catalysts of partial methane oxidation into synthesis gas were obtained by electrochemical modification of the surface of sintered FeCrAl alloy fibers in an ionic liquid BMIM-NTf, with further introduction of platinum nanoparticles. It ...
Supercritical (SC) fluid technologies are well-established methods in modern green chemical synthesis. Using SC fluids as solvents instead of traditional liquids gives benefits of higher diffusivity and lower viscosity, which allows mass transfer intensifi ...
This paper describes the synthesis of Pd-containing catalysts based on nonfunctionalized hypercrosslinked polystyrene via impregnation with Pd acetate. Developed Pd nanoparticulate catalyst allowed achieving conversion of aryl halide up to 90% in Suzuki cr ...
Activated carbon fibers (ACFs) with surface modified by a diethylene triamine (DETA) are synthesized for the abatement of formaldehyde in gas phase at low concentration. Adsorbents with several DETA loadings were tested and characterized. The amount of DET ...
We have carried out a systematic investigation of the critical activation parameters (i.e., final temperature (673-1273 K), atmosphere (He vs. O-2/He), and final isothermal hold (1 min-15 h) on the generation of "alpha-sites", responsible for the direct N2 ...
We have investigated the catalytic effect of the beta-phase PdZn alloy on selective gas-phase hydrogenation of 2-methyl-3-butyn-2-ol over Pd/ZnO using Pd/Al2O3 as a benchmark. Activation (in H-2) of Pd/ZnO to 973 K generated a beta-phase PdZn alloy (from X ...
The catalytic effect of nitrogen incorporation into Mo on hydrogenation (of -NO2 to -NH2 in nitrobenzene to aniline) and hydrogenolysis (of -C?O in benzaldehyde to toluene) processes has been assessed. Bulk Mo was prepared by temperature programmed reducti ...
This work is addressed to the phenomenon of catalyst deactivation taking place during the repeated uses in the reaction of Suzuki-Miyaura (S-M) cross-coupling, which is widely applied in industry for C-C bond formation. Ligandless catalysts based on Pd(0) ...
