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In this thesis, the electrochemical promotion of lr and Rh based catalysts was studied for the complete combustion of ethylene and propylene. The study was performed by using two types of electrocatalytical cells: a classical, pellet type cell and a tubula ...
A model for the electrochem. promotion induced by electrochem. generated promoting species is proposed. The formation rate of promoters is assumed to be proportional to the availability of free surface sites at the solid electrolyte/catalyst/gas three-phas ...
A review with refs. concerning electrochem. promotion of catalysis is presented. Recent progress made in our lab. in the field of electrochem. promotion of heterogeneous catalytic gas reactions is presented. The phenomenon consists of non-Faradaic modifica ...
In this work, the voltammetric charge and work function of Rh catalyst were studied to clarify the origin of electrochem. promotion. The measures were carried on at 375 Deg, either in a non-reactive oxygen/helium gas mixt. or under complete oxidn. of propy ...