Publications de Ignacio Rintoul

Limit Of Applicability Of The Monomer-Enhanced Mechanism For Radical Generation In Persulfate Initiated Polymerization Of Acrylamide

Jutta Christine Wandrey, Ignacio Rintoul

The limit of applicability of the monomer-enhanced mechanism as dominant mechanism ruling the initiation process of the polymerization of acrylamide (AM) initiated with potassium persulfate (K2S2O8) has been determined The kinetics and mechanisms for radic ...

Universidad Nacional del Sur y Consejo Nacional de Investigaciones Científicas y Técnicas2010

Magnetic Field Effects on the Copolymerization of Water-Soluble and Ionic Monomers

Jutta Christine Wandrey, Ignacio Rintoul

2009

Radical homo-and copolymerization of acrylamide and ionic monomers in weak magnetic field

Jutta Christine Wandrey, Ignacio Rintoul

The synergy between magnetic ﬁeld (MF) and electrostatic interactions on the kinetics of radical homopolymerization of acrylamide (AM), acrylic acid (AA), its ionized form acrylate (A ...

2008

Magnetic field effects on the free radical solution polymerization of acrylamide

Jutta Christine Wandrey, Ignacio Rintoul

2007

Magnetic and electrostatic effects on the polymerization of water-soluble monomers

Ignacio Rintoul

Free radical polymerization is the most frequently used technique to produce synthetic polymers. They represent more than 25% of the total volume of materials made by the mankind. 3% thereof correspond to water soluble polymers with annual growth rates est ...

EPFL2006

Approach To Predict Copolymer Compositions in Case of Variable Monomer Reactivity

Jutta Christine Wandrey, Ignacio Rintoul

An anal. approach to predict copolymer compns. is presented for the particular case that the reactivity of one monomer (B) alters under the influence of one measurable medium parameter. Terpolymn. math. treatment was applied to binary systems (A/B), which ...

American Chemical Society2005

Polymerization of ionic monomers in polar solvents: kinetics and mechanism of the free radical copolymerization of acrylamide/acrylic acid

Jutta Christine Wandrey, Ignacio Rintoul

A precise data set describing the kinetics of the free radical copolymn. of acrylamide/acrylic acid (AM/AA) in the range of low total monomer concn. as a function of the pH, total monomer concn., initiator concn., and comonomer ratio is presented. Strong i ...

2005