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Free radical polymerization is the most frequently used technique to produce synthetic polymers. They represent more than 25% of the total volume of materials made by the mankind. 3% thereof correspond to water soluble polymers with annual growth rates est ...
The synergy between magnetic field (MF) and electrostatic interactions on the kinetics of radical homopolymerization of acrylamide (AM), acrylic acid (AA), its ionized form acrylate (A ...
An anal. approach to predict copolymer compns. is presented for the particular case that the reactivity of one monomer (B) alters under the influence of one measurable medium parameter. Terpolymn. math. treatment was applied to binary systems (A/B), which ...
A precise data set describing the kinetics of the free radical copolymn. of acrylamide/acrylic acid (AM/AA) in the range of low total monomer concn. as a function of the pH, total monomer concn., initiator concn., and comonomer ratio is presented. Strong i ...
The limit of applicability of the monomer-enhanced mechanism as dominant mechanism ruling the initiation process of the polymerization of acrylamide (AM) initiated with potassium persulfate (K2S2O8) has been determined The kinetics and mechanisms for radic ...
Universidad Nacional del Sur y Consejo Nacional de Investigaciones Científicas y Técnicas2010