Publications de Marie-Line Lehaire

Water-Exchange Study Revealed Unexpected Substitution Behavior of [(CO)2(NO)Re(H2O)3]2+ in Aqueous Media

André Merbach, Lothar Helm, Pascal Grundler, Marie-Line Lehaire

The pH-dependent water-exchange rates of [(CO)2(NO)Re(H2Ocis)2(H2Otrans)]2+ (1) in aq. media were investigated by means of 17O NMR spectroscopy at 298 K. Because of the low pKa value found for 1 (pKa = 1.4 ± 0.3), the water-exchange rate const. kobsH2Otran ...

2006

Reactivity of the novel organometallic aqua-ion [(CO)2(NO)Re(H2O) 3]2+: Kinetics of H2O substitution and 17O exchange of CO ligands

André Merbach, Pascal Grundler, Marie-Line Lehaire

2005

Structures and host-guest chemistry of self-assembled organometallic macrocycles

Marie-Line Lehaire

EPFL2004

Stabilization of molecular LiF, LiFHF, and Na2SiF6 using metallamacrocyclic hosts

Kay Severin, Marie-Line Lehaire

The molecular forms of LiF, LiFHF and Na2SiF6 have been stabilized using trinuclear metallamacrocyclic complexes of (cymene)Ru-II, (Cp*)Rh-III and (Cp*)Ir-III as specific receptors. The host-guest complexes were characterized by NMR spectroscopy and single ...

2003