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Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Rosario Scopelliti, Euro Solari, Albert Ruggi, Vincent Artero, Fiorella Lucarini

Cobalt(II) complexes featuring hexadentate amino-pyridyl ligands have been recently discovered as highly active catalysts for the Hydrogen Evolution Reaction (HER), whose high performance arises from the possibility of assisting proton transfer processes v ...

ROYAL SOC CHEMISTRY2023

Fluorinated Tetraarylethenes: Universal Tags for the Synthesis of Solid State Luminogens

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Euro Solari, Albert Ruggi, Abdusalom Suleymanov, Thibault Jacques Marie Damiens Vanrapenbusch, Barbara Maja Kraus

The aggregation-induced emission properties of tetraarylethenes (TAEs) have led to numerous applications in chemistry, biology, and materials science. Herein, we describe two fluorinated tetraarylethenes, which can be employed as universal tags for the syn ...

Wiley-VCH Verlag GmbH2022

Novel cationic 1,2,4-selenadiazoles: synthesis via addition of 2-pyridylselenyl halides to unactivated nitriles, structures and four-center SeMIDLINE HORIZONTAL ELLIPSISN contacts

Euro Solari, Alexander Tskhovrebov

2-Pyridylselenyl halides undergo facile coupling with a triple CN bond of unactivated nitriles. Unprecedented heterocyclization allowed the preparation of a novel class of cationic 1,2,4-selenadiazoles in remarkably high yields. Cationic 1,2,4-selenadiazol ...

ROYAL SOC CHEMISTRY2021

Unsymmetrical Trifluoromethyl Methoxyphenyl beta-Diketones: Effect of the Position of Methoxy Group and Coordination at Cu(II) on Biological Activity

Euro Solari

Copper(II) complexes with 1,1,1-trifluoro-4-(4-methoxyphenyl)butan-2,4-dione (HL1) were synthesized and characterized by elemental analysis, FT-IR spectroscopy, and single crystal X-ray diffraction. The biological properties of HL1 and cis-[Cu(L1)(2)(DMSO) ...

MDPI2021

Novel cationic 1,2,4-selenadiazoles: synthesis via addition of 2-pyridylselenyl halides to unactivated nitriles, structures and four-center Se center dot center dot center dot N contacts (vol 50, pg 10689, 2021)

Euro Solari

ROYAL SOC CHEMISTRY2021

Rationalizing Photo-Triggered Hydrogen Evolution Using Polypyridine Cobalt Complexes: Substituent Effects on Hexadentate Chelating Ligands

Rosario Scopelliti, Farzaneh Fadaei Tirani, Euro Solari

Four novel polypyridine cobalt(II) complexes were developed based on a hexadentate ligand scaffold bearing either electron-withdrawing (-CF3) or electron-donating (-OCH3) groups in different positions of the ligand. Experiments and theoretical calculations ...

WILEY-V C H VERLAG GMBH2021

Thermodynamics and kinetics of protonated merocyanine photoacids in water

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Euro Solari, Daniel Maria Busiello, Cristian Pezzato, Stefano Zamuner, Cesare Berton

Metastable-state photoacids (mPAHs) are chemical species whose photo-activated state is long-lived enough to allow for proton diffusion. Liao's photoacid (1) represents the archetype of mPAHs, and is being widely used on account of its unique capability to ...

2020

Euro Solari

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Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Fluorinated Tetraarylethenes: Universal Tags for the Synthesis of Solid State Luminogens

Novel cationic 1,2,4-selenadiazoles: synthesis via addition of 2-pyridylselenyl halides to unactivated nitriles, structures and four-center SeMIDLINE HORIZONTAL ELLIPSISN contacts

Unsymmetrical Trifluoromethyl Methoxyphenyl beta-Diketones: Effect of the Position of Methoxy Group and Coordination at Cu(II) on Biological Activity

Novel cationic 1,2,4-selenadiazoles: synthesis via addition of 2-pyridylselenyl halides to unactivated nitriles, structures and four-center Se center dot center dot center dot N contacts (vol 50, pg 10689, 2021)

Rationalizing Photo-Triggered Hydrogen Evolution Using Polypyridine Cobalt Complexes: Substituent Effects on Hexadentate Chelating Ligands

Thermodynamics and kinetics of protonated merocyanine photoacids in water

Azo-MICs: Redox-Active Mesoionic Carbene Ligands Derived from Azoimidazolium Dyes

Crystalline Polymers Based on Dative Boron–Nitrogen Bonds and the Quest for Porosity

Synthesis of aminyl biradicals by base-induced Csp3–Csp3 coupling of cationic azo dyes

Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Fluorinated Tetraarylethenes: Universal Tags for the Synthesis of Solid State Luminogens

Novel cationic 1,2,4-selenadiazoles: synthesis via addition of 2-pyridylselenyl halides to unactivated nitriles, structures and four-center SeMIDLINE HORIZONTAL ELLIPSISN contacts

Unsymmetrical Trifluoromethyl Methoxyphenyl beta-Diketones: Effect of the Position of Methoxy Group and Coordination at Cu(II) on Biological Activity

Novel cationic 1,2,4-selenadiazoles: synthesis via addition of 2-pyridylselenyl halides to unactivated nitriles, structures and four-center Se center dot center dot center dot N contacts (vol 50, pg 10689, 2021)

Rationalizing Photo-Triggered Hydrogen Evolution Using Polypyridine Cobalt Complexes: Substituent Effects on Hexadentate Chelating Ligands

Thermodynamics and kinetics of protonated merocyanine photoacids in water

Azo-MICs: Redox-Active Mesoionic Carbene Ligands Derived from Azoimidazolium Dyes

Crystalline Polymers Based on Dative Boron–Nitrogen Bonds and the Quest for Porosity

Synthesis of aminyl biradicals by base-induced Csp3–Csp3 coupling of cationic azo dyes