Philip Pattison

Cette personne n’est plus à l’EPFL

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Publications associées (86)

The Intricate Structural Chemistry of MII2nLn-Type Assemblies

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Philip Pattison, Euro Solari, Giacomo Cecot, Mathieu Jérémie Marmier

The reaction of cis-blocked, square-planar MII complexes with tetratopic N-donor ligands is known to give metallasupramolecular assemblies of the formula M2nLn. These assemblies typically adopt barrel-like structures, with the ligands paneling the sides of ...

2017

Discovery of S···C≡N Intramolecular Bonding in a Thiophenylcyanoacrylate-Based Dye: Realizing Charge Transfer Pathways and Dye···TiO

Philip Pattison, Lei Zhang

2017

Crystal growth, structure and magnetic properties of Ca10Cr7O28

Philip Pattison, Sándor Tóth, Yogesh Singh

Institute of Physics2017

Application of micro X-ray diffraction to investigate the reaction products formed by the alkali–silica reaction in concrete structures

Gervais Chapuis, Alla Arakcheeva, Philip Pattison

Alkali-silica reaction (ASR) is one of the most important deterioration mechanisms in concrete leading to substantial damages of structures worldwide. Synchrotron-based micro-X-ray diffraction (micro-XRD) was employed to characterize the mineral phases for ...

Pergamon-Elsevier Science Ltd2016

Thermal induced structural properties of silver(I) sulphate (Ag2SO4)

Philip Pattison

The crystal structures of silver(I) sulphate, Ag2SO4, have been investigated as a function of temperature. A main feature is the phase transition from the low-temperature ordered phase, F ddd, to the high-temperature disordered phase, P63/mmc. In particula ...

Wiley-Blackwell2016

Surface functionalization of dinuclear clathrochelates via Pd-catalyzed cross-coupling reactions: facile synthesis of polypyridyl metalloligands

Rosario Scopelliti, Kay Severin, Philip Pattison, Euro Solari, Giacomo Cecot, Mathieu Jérémie Marmier

Dinuclear clathrochelate complexes are easily accessible by reaction of zinc(II) triflate or cobalt(II) nitrate with arylboronic acids and phenoldioximes. The utilization of brominated arylboronic acids and/or brominated phenoldioximes allows preparing cla ...

2016

The Ligand Aspect Ratio as a Decisive Factor for the Self-Assembly of Coordination Cages

Rosario Scopelliti, Kay Severin, Philip Pattison, Euro Solari, Konstantin Zhurov, Suzanne Maria Jansze, Giacomo Cecot, Matthew David Wise, Alba Finelli

It is possible to control the geometry and the composition of metallasupramolecular assemblies via the aspect ratio of their ligands. This point is demonstrated for a series of iron- and palladium-based coordination cages. Functionalized clathrochelate com ...

2016

Probing structural chirality with high-energy synchrotron radiation

Philip Pattison

International Union of Crystallography2016

Neutral Aminyl Radicals Derived from Azoimidazolium Dyes

Rosario Scopelliti, Kay Severin, Henrik Moodysson Rønnow, Matthew Wodrich, Andrzej Sienkiewicz, Ivica Zivkovic, Philip Pattison, Euro Solari, Laurent Alexis Clément Vannay, Alexander Tskhovrebov

The synthesis and characterization of a new class of neutral aminyl radicals is reported. Monoradicals were obtained by reduction of azoimidazolium dyes with potassium. Structural, spectroscopic, and computational data suggest that the spin density is cent ...

2016

Carboxylic Acid Functionalized Clathrochelate Complexes: Large, Robust, and Easy-to-Access Metalloligands

Rosario Scopelliti, Kay Severin, Kurt Schenk, Philip Pattison, Euro Solari, Mathieu Jérémie Marmier, Matthew David Wise

Polycarboxylate ligands are among the most important building blocks for the synthesis of metal–organic frameworks (MOFs). The ability to access these ligands in an efficient way is of key importance for future applications of MOFs. Here, we demonstrate th ...

2016

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