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Andrew Douglas Phillips

Cette personne n’est plus à l’EPFL

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Publications associées (17)

Suzuki Coupling Reactions in Ether-Functionalized Ionic Liquids: The Importance of Weakly Interacting Cations

Paul Joseph Dyson, Zhaofu Fei, Andrew Douglas Phillips, Christian Hartinger, Yuehui Li, Xuemei Yang

Imidazolium- and pyridinium-based ionic liqs. with ether/polyether substituents have been evaluated as solvents for palladium-catalyzed Suzuki C-C coupling reactions. In general, reactions proceed more efficiently in these solvents compared to other ionic ...

2008

Linked Metal-cluster Systems: Isolation and Characterization of {anti-[(p-cymene)RuCl]-m-[k 2-P,P';k 1-P''-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

Paul Joseph Dyson, Rosario Scopelliti, Andrew Douglas Phillips, Christian Hartinger, Hisham Ben Hamidane, Zoltan Beni

The new mixed-metal complex {anti-[(p-cymene)RuCl]-m-[k 2-P,P';k 1-P''-(PPh2CH2)3CMe]-[AuCl]}PF6 and its cluster deriv. {anti-[(p-cymene)RuCl]-m-[k 2-P,P';k 1-P''-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2 have been prepd. and characterized. Notably, NMR sp ...

Springer US2008

(Pentamethylcyclopentadienyl)iridium-PTA (PTA = 1,3,5-Triaza-7-phosphaadamantane) Complexes and Their Application in Catalytic Water Phase Carbon Dioxide Hydrogenation

Paul Joseph Dyson, Gabor Laurenczy, Andrew Douglas Phillips

The water-soluble iridium(III) complexes [CpIr(PTA)Cl2] (1) and [CpIr(PTA)2Cl]Cl (2) (PTA = 1,3,5-triaza-7-phosphaadamantane) have been synthesised and characterised by spectroscopy and X-ray crystallography. The complexes were evaluated as catalyst prec ...

2008

Facile, thermo-reversible cycloaddition of small molecules to a ruthenium(II) arene-diketiminate

Paul Joseph Dyson, Rosario Scopelliti, Gabor Laurenczy, Andrew Douglas Phillips

Formation of a vacant coordination site on a Ru center permits an unusual binding of small molecules such as ethylene, acetylene, and dihydrogen, resulting in the transformation of the chelating β-diketiminate ligand to a β-diimine. These represe ...

2007

Development of Ruthenium Antitumor Drugs that Overcome Multidrug Resistance Mechanisms

Paul Joseph Dyson, Rosario Scopelliti, Wee Han Ang, Andrew Douglas Phillips, Claudine Scolaro, Gianni Sava

Organometallic ruthenium(II) complexes of the general formula [Ru(η6-p-cymene)Cl2(L)] and [Ru(η6-p-cymene)Cl(L)2][BPh4] with modified phenoxazine- and anthracene-based multidrug resistanc ...

2007

In Vitro Evaluation of Rhodium and Osmium RAPTA Analogues: The Case for Organometallic Anticancer Drugs Not Based on Ruthenium

Paul Joseph Dyson, Gabor Laurenczy, Wee Han Ang, Andrew Douglas Phillips, Antoine Dorcier

Reaction of the dimer [(η5-C5Me5)RhCl(μ2-Cl)]2 with 2 or 4 equiv of the water-soluble phosphine 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (pta) affords [Rh(η5-C5Me< ...

2006

Synthesis, Characterization, and in Vitro Evaluation of Novel Ruthenium(II) η6-Arene Imidazole Complexes

Paul Joseph Dyson, Rosario Scopelliti, Andrew Douglas Phillips, Claudine Scolaro, Gianni Sava

Ten complexes of general formula [Ru(η6-arene)Cl2(L)], [Ru(η6-arene)Cl(L)2][X], and [Ru(η6-arene)(L)3][X]2 (η6-arene = benzene, p-cymene; L = imidazole, ...

2006

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Suzuki Coupling Reactions in Ether-Functionalized Ionic Liquids: The Importance of Weakly Interacting Cations

Paul Joseph Dyson, Zhaofu Fei, Andrew Douglas Phillips, Christian Hartinger, Yuehui Li, Xuemei Yang

2008

Linked Metal-cluster Systems: Isolation and Characterization of {anti-[(p-cymene)RuCl]-m-[k 2-P,P';k 1-P''-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

Paul Joseph Dyson, Rosario Scopelliti, Andrew Douglas Phillips, Christian Hartinger, Hisham Ben Hamidane, Zoltan Beni

Springer US2008

(Pentamethylcyclopentadienyl)iridium-PTA (PTA = 1,3,5-Triaza-7-phosphaadamantane) Complexes and Their Application in Catalytic Water Phase Carbon Dioxide Hydrogenation

Paul Joseph Dyson, Gabor Laurenczy, Andrew Douglas Phillips

2008

In Vitro Evaluation of Rhodium and Osmium RAPTA Analogues: The Case for Organometallic Anticancer Drugs Not Based on Ruthenium

Paul Joseph Dyson, Gabor Laurenczy, Wee Han Ang, Andrew Douglas Phillips, Antoine Dorcier

Reaction of the dimer [(η5-C5Me5)RhCl(μ2-Cl)]2 with 2 or 4 equiv of the water-soluble phosphine 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (pta) affords [Rh(η5-C5Me< ...

2006

Development of Ruthenium Antitumor Drugs that Overcome Multidrug Resistance Mechanisms

Paul Joseph Dyson, Rosario Scopelliti, Wee Han Ang, Andrew Douglas Phillips, Claudine Scolaro, Gianni Sava

Organometallic ruthenium(II) complexes of the general formula [Ru(η6-p-cymene)Cl2(L)] and [Ru(η6-p-cymene)Cl(L)2][BPh4] with modified phenoxazine- and anthracene-based multidrug resistanc ...

2007

Facile, thermo-reversible cycloaddition of small molecules to a ruthenium(II) arene-diketiminate

Paul Joseph Dyson, Rosario Scopelliti, Gabor Laurenczy, Andrew Douglas Phillips

2007

Synthesis, Characterization, and in Vitro Evaluation of Novel Ruthenium(II) η6-Arene Imidazole Complexes

Paul Joseph Dyson, Rosario Scopelliti, Andrew Douglas Phillips, Claudine Scolaro, Gianni Sava

Ten complexes of general formula [Ru(η6-arene)Cl2(L)], [Ru(η6-arene)Cl(L)2][X], and [Ru(η6-arene)(L)3][X]2 (η6-arene = benzene, p-cymene; L = imidazole, ...

2006