Paul Gratia

Cette personne n’est plus à l’EPFL

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Publications associées (20)

High Open-Circuit Voltage: Fabrication of Formamidinium Lead Bromide Perovskite Solar Cells Using Fluorene-Dithiophene Derivatives as Hole-Transporting Materials

Michael Graetzel, Neha Arora, Mohammad Khaja Nazeeruddin, Paul Gratia, Filippo de Angelis, Mohammad Ibrahim Dar, Gwénolé Jean Jacopin, Sadig Aghazada

Four different fluorene dithiophene derivative-based hole-transporting materials (HTMs) (SO7-10) have been synthesized via a facile route and were successfully used in the fabrication of formamidinium lead bromide perovskite solar cells. Detailed character ...

Amer Chemical Soc2016

Branched methoxydiphenylamine-substituted fluorene derivatives as hole transporting materials for high-performance perovskite solar cells

Michael Graetzel, Paul Gratia, Mohammad Khaja Nazeeruddin, Michael Saliba, Taisuke Matsui, Simona Urnikaite

Small-molecule hole transporting materials based on methoxydiphenylamine-substituted fluorene fragments were synthesized and incorporated into a perovskite solar cell, which displayed a power conversion efficiency of up to 19.96%, one of the highest conver ...

Royal Soc Chemistry2016

A highly hindered bithiophene-functionalized dispiro-oxepine derivative as an efficient hole transporting material for perovskite solar cells

Mohammad Khaja Nazeeruddin, Kasparas Rakstys, Paul Gratia, Peng Gao, Sanghyun Paek, Yonghui Lee, Kyung Taek Cho, Muhammad Sohail

Dimethoxydiphenylamine-substituted dispiro-oxepine derivative 2,2',7,7'-tetrakis-(N,N'-di-4-methoxyphenylamine)dispiro-[fluorene-9,4'-dithieno(3,2-c:2',3'-e]oxepine-6',9 ''-fluorene] (DDOF) has been designed and synthesized using a facile synthetic route. ...

Royal Society of Chemistry2016

Benzotrithiophene-Based Hole-Transporting Materials for 18.2% Perovskite Solar Cells

Michael Graetzel, Paul Gratia, Mohammad Khaja Nazeeruddin, Iwan Zimmermann, Cristina Roldán Carmona, Sadig Aghazada, Inés Garcia Benito

New star-shaped benzotrithiophene (BTT)-based hole-transporting materials (HTM) BTT-1, BTT-2 and BTT-3 have been obtained through a facile synthetic route by crosslinking triarylamine-based donor groups with a benzotrithiophene (BTT) core. The BTT HTMs wer ...

Wiley-VCH Verlag GmbH2016

Intrinsic Halide Segregation at Nanometer Scale Determines the High Efficiency of Mixed Cation/Mixed Halide Perovskite Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Kevin Sivula, Filippo de Angelis, Iwan Zimmermann, Giulia Grancini, Yonghui Lee, Paul Gratia, Xavier Adrian Jeanbourquin

Compositional engineering of a mixed cation/mixed halide perovskite in the form of (FAP-bI(3))(0.85)(MAPbBr(3))(0.15) is one of the most effective strategies to obtain record-efficiency perovskite solar cells. However, the perovskite self-organization upon ...

2016

Enhanced TiO2/MAPbI(3) Electronic Coupling by Interface Modification with PbI2

Mohammad Khaja Nazeeruddin, Giulia Grancini, Paul Gratia, Filippo de Angelis, Iwan Zimmermann, Cristina Roldán Carmona

Amer Chemical Soc2016

Small molecule hole transporting material for optoelectronic and photoelectrochemical devices

Michael Graetzel, Mohammad Khaja Nazeeruddin, Paul Gratia

The present invention relates to a compound of formula (I) based on carbazole substituted by diphenylamine and used as organic hole conductors or hole transporting material in a optoelectronic or photoelectrochemical device. (I), D being being selected fro ...

2016

A Methoxydiphenylamine-Substituted Carbazole Twin Derivative: An Efficient Hole-Transporting Material for Perovskite Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Antonio Abate, Paul Gratia

The small-molecule-based hole-transporting material methoxydiphenylamine-substituted carbazole was synthesized and incorporated into a CH3NH3PbI3 perovskite solar cell, which displayed a power conversion efficiency of 16.91%, the second highest conversion ...

Wiley-VCH Verlag GmbH2015

High efficiency methylammonium lead triiodide perovskite solar cells: the relevance of non-stoichiometric precursors

Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Gao, Giulia Grancini, Paul Gratia, Iwan Zimmermann, Cristina Roldán Carmona

Methylammonium lead iodide perovskite solar cells with improved performance and stability have been successfully prepared by using a non-stoichiometric PbI2 : CH3NH3I ratio in the precursor solution, and yield a power conversion efficiency (PCE) of above 1 ...

Royal Soc Chemistry2015

Toward Higher Photovoltage: Effect of Blocking Layer on Cobalt Bipyridine Pyrazole Complexes as Redox Shuttle for Dye-Sensitized Solar Cells

Michael Graetzel, Jun Ho Yum, Thomas Moehl, Aravind Kumar Chandiran, Paul Gratia, Junghyun Yoon

Fluorine-doped tin-oxide (FTO) transparent conducting substrates, for use in cobalt bis(bipyridine pyrazole) complex based dye-sensitized solar cells (DSCs), were compared using the conventional TiCl4 treatment with conformal TiO2 blocking layers formed by ...

American Chemical Society2014

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