Publications de Svetlana Eliseeva

Synthesis and spectroscopy of anionic tridentate benzimidazole-pyridine carboxylate and tetrazolate chromophore ligands

We report on seven new anionic benzimidazole-pyridine carboxylate and tetrazolate tridentate (NNO)-N-boolean AND-O-boolean AND and (NNN)-N-boolean AND-N-boolean AND ligands that are modified with chromophore (phenyl, biphenyl, naphthyl) and solubilizing gr ...

Elsevier2015

Influence of Symmetry on the Luminescence and Radiative Lifetime of Nine-Coordinate Europium Complexes

Rosario Scopelliti, Jean-Claude Bünzli, Svetlana Eliseeva

Homoleptic mononuclear nine-coordinate lanthanum(III) and europium(III) tris-complexes [Ln(N^N^O)3]·nH2O with two tridentate N-benzyl-benzimidazole pyridine-2-carboxylates exhibit a rare C3-symmetry of the lanthanide coordination polyhedron in the solid st ...

Amer Chemical Soc2015

Tridentate Benzimidazole-Pyridine-Tetrazolates as Sensitizers of Europium Luminescence

Rosario Scopelliti, Jean-Claude Bünzli, Svetlana Eliseeva

We report on new anionic tridentate benzimidazole-pyridine-tetrazolate ligands that form neutral 3:1 complexes with trivalent lanthanides. The ligands are UV-absorbing chromophores that sensitize the red luminescence of europium with energy-transfer effici ...

Amer Chemical Soc2014

The luminescence of NaxEu3+(2−x)/3MoO4 scheelites depends on the number of Eu-clusters occurring in their incommensurately modulated structure

Gervais Chapuis, Jean-Claude Bünzli, Alla Arakcheeva, Philip Pattison, Svetlana Eliseeva, Dmitry Logvinovich

Scheelite related compounds with general formula Mn(XO4)m are of interest owing to their optical properties, stability and relatively simple preparation. Eu3+-containing scheelites are considered as red emitting phosphors and the main factors affecting the ...

2012

Synthesis and Photophysical Properties of Ln(III)-DOTA-Bipy Complexes and Ln(III)-DOTA-Bipy-Ru-II Coordination Conjugates

Jean-Claude Bünzli, Svetlana Eliseeva

The synthesis and the systematic and comparative photo-physical study of a series of visible (Eu-III, Tb-III) and NIR-emitting (Nd-III, Yb-III) lanthanide complexes (Ln(2)L) and ruthenium lanthanide coordination conjugates (Ln(2)LRu) are reported. The Gd-I ...

Wiley-Blackwell2010

Lanthanide luminescence for functional materials and bio-sciences

Jean-Claude Bünzli, Svetlana Eliseeva

Recent startling interest for lanthanide luminescence is stimulated by the continuously expanding need for luminescent materials meeting the stringent requirements of telecommunication, lighting, electroluminescent devices, (bio-)analytical sensors and bio ...

Royal Society of Chemistry2010

Multiphoton-Excited Luminescent Lanthanide Bioprobes: Two- and Three-Photon Cross Sections of Dipicolinate Derivatives and Binuclear Helicates

Jean-Claude Bünzli, Majed Chergui, Anne-Sophie Chauvin, Svetlana Eliseeva, Frank van Mourik, Bo Song, Andrea Cannizzo, Gerald Auböck

Multiphoton excited luminescent properties of water-soluble EuIII and TbIII complexes with derivatives of dipicolinic acid functionalized with a polyoxyethylene pendant arm and terminal groups, [Eu(LOMe)3]3-, [Eu(LNH2)3]3-, and [Tb(LOH)3]3-, as well as of ...

2010

N-Aryl Chromophore Ligands for Bright Europium Luminescence

Rosario Scopelliti, Jean-Claude Bünzli, Svetlana Eliseeva

Sterically hindered N-aryl-benzimidazole pyridine-2-carboxylic acids (aryl = phenyl, 4-biphenyl, 2-naphthyl) readily form homoleptic, neutral, nine-coordinate europium complexes which display efficient sensitized luminescence in solid state and in dichloro ...

American Chemical Society2010

Designing Simple Tridentate Ligands for Highly Luminescent Europium Complexes

Rosario Scopelliti, Jean-Claude Bünzli, Svetlana Eliseeva

A series of tridentate benz- ACHTUNGTRENUNGimidazole-substituted pyridine-2-carboxylic acids have been prepared with a halogen, methyl or alkoxy group in the 6-position of the benzimidazole ring, which additionally contains a solubilising N-alkyl chain. Th ...

2009

Dimeric Complexes of Lanthanide(III) Hexafluoroacetylacetonates with 4-Cyanopyridine N-Oxide: Syn thesis, Crystal Structure, Magnetic and Photoluminescent Properties

Jean-Claude Bünzli, Frédéric Gumy, Svetlana Eliseeva

A series of new mixed-ligand lanthanide complexes [Ln(hfa)3(4-cpyNO)]2 (Ln = SmIII-HoIII and TmIII; hfa- = hexafluoroacetylacetonate; 4-cpyNO = 4-cyanopyridine N-oxide) have been synthesised by treating the corresponding lanthanide hexafluoroacetylacetonat ...

2006