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Pekka Eero Peljo

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Publications associées (48)

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The Mn(III)/Mn(II) redox couple with a standard potential of +1.51 V vs . SHE has drawn interest for the design of V/Mn redox flow battery (RFB). However, Mn(III) disproportionation leads to a loss of capacity, an increase of pressure drop and electrode pa ...

Wiley2020

Structure and reactivity of the polarised liquid–liquid interface: what we know and what we do not

Hubert Girault, Astrid Johana Olaya Avendano, Pekka Eero Peljo, Grégoire Clément Gschwend

Charge transfer phenomena at the interface between two immiscible electrolyte solutions (ITIES) are electrochemical reactions taking place in soft media. Owing to their liquid nature, the ITIES shows a large panel of electrochemical reactions including ele ...

2020

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Low-grade heat (below 200 °C) is available in vast quantities from industry, or from standard roof-top solar thermal collectors. However, the production of electric power from these heat sources is challenging with existing technologies. Thermally regenera ...

2020

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All redox flow batteries suffer from low energy storage density in comparison with conventional Li-ion batteries. However, this issue can be mitigated by utilization of solid energy storage materials to enhance the energy storage capacity. In this paper we ...

2019

Mechanistic study of the photo‐generation of hydrogen by decamethylruthenocene

Hubert Girault, Pekka Eero Peljo, Manuel Alejandro Méndez Agudelo, Heron Vrubel, Micheal Diarmaid Scanlon, Laurent Alexis Clément Vannay, Sunny Isaïe Maye, Lucie Josette Renée Rivier

Hydrogen evolution by decamethylruthenocene (Cp*2RuII) was studied in detail highlighting that metallocenes are capable of photo‐reducing hydrogen without the need of an additional sensitizer. Electrochemical, gas chromatographic and spectroscopic (UV/vis, ...

2019

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The absence of general theoretical models describing linear sweep voltammetry (LSV) or cyclic voltammetry (CV) responses for soluble-insoluble systems such as one-step electrodeposition reactions under quasi-reversible condition makes it difficult to extra ...

2018

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Chaotropes such as urea can break the structure of water, weakening the hydrophobic effect and reducing aggregation. Here, we investigated how the addition of urea affects the transfer of ions and cationic dyes across the interface between immiscible elect ...

2018

Gold Nanofilms at Liquid–Liquid Interfaces: An Emerging Platform for Redox Electrocatalysis, Nanoplasmonic Sensors, and Electrovariable Optics

Pekka Eero Peljo, Micheal Diarmaid Scanlon, Evgeny Smirnov, Thomas James Stockmann

The functionality of liquid–liquid interfaces formed between two immiscible electrolyte solutions (ITIES) can be markedly enhanced by modification with supramolecular assemblies or solid nanomaterials. The focus of this Review is recent progress involving ...

2018

Chronoamperometry was used to study the dynamics of Pt nanoparticle (NP) collision with an inert ultramicroelectrode via electrocatalytic amplification (ECA) towards hydrogen evolution reaction. First, ECA and dynamic light scattering (DLS) results reveal ...

2018

Gold Raspberry-Like Colloidosomes Prepared at the Water-Nitromethane Interface

Hubert Girault, Pekka Eero Peljo, Evgeny Smirnov

Here, we propose a simple shake-flask method to produce micron-size colloidosomes from a liquid-liquid interface functionalized with a gold nanoparticle film. A step-by-step extraction process of an organic phase partially miscible with water led to the fo ...

2018