Publications de Loris Giovanni Lombardo

Deep Eutectic Solvents Formed by Complex Hydrides: A New Class of Hydrogen‐Rich Liquid

Andreas Züttel, Thi Ha My Pham, Loris Giovanni Lombardo

Deep eutectic solvents (DESs) are novel mixtures that exhibit a significant depression in melting points compared to their individual components. This work finds that combining tetrabutylammonium borohydride (TBABH) with ammonia borane (AB) yields new, sta ...

Wiley2025

Engineering Ru Nanoparticle Size and Metal-support Interactions for Enhanced Catalytic Hydrogen Combustion

Andreas Züttel, Thi Ha My Pham, Loris Giovanni Lombardo

Catalytic hydrogen combustion (CHC) plays a crucial role in enhancing the safety and efficiency of fuel cells and electrolysers, thereby promoting the H2 economy. To increase the catalytic activity of supported metal particles for CHC, the active surface a ...

Royal Society of Chemistry2025

Synthesis, Crystal Structure, and Hydrogen Storage Properties of an AB3-Based Alloy Synthesized by Disproportionation Reactions of AB2-Based Alloys

Loris Giovanni Lombardo

Hydrogen storage materials store hydrogen in their atomic states, enabling more compact and safer storage methods compared to those for gaseous and liquid hydrogen. Although various types of hydrogen storage materials have been reported, new materials with ...

AMER CHEMICAL SOC2025

The Effect of Y Content on Structural and Sorption Properties of A(2)B(7)-Type Phase in the La-Y-Ni-Al-Mn System

Andreas Züttel, Loris Giovanni Lombardo

Metal hydrides are an interesting group of chemical compounds, able to store hydrogen in a reversible, compact and safe manner. Among them, A(2)B(7)-type intermetallic alloys based on La-Mg-Ni have attracted particular attention due to their high electroch ...

MDPI2023

Selective Borohydride Oxidation Reaction on Nickel Catalyst with Anion and Cation Exchange Ionomer for High-Performance Direct Borohydride Fuel Cells

Andreas Züttel, Thi Ha My Pham, Loris Giovanni Lombardo, Heena Yang, Mo Li, Youngdon Ko

Direct borohydride fuel cells (DBFCs) operate with liquid H2O2 and a high-energy-density NaBH4 solution. A facile, direct synthesis method using a non-noble nickel catalyst for the DBFC anode is shown. The complex anode reaction with an anion-exchange iono ...

WILEY-V C H VERLAG GMBH2022

Effect of Co-Substitution on Hydrogen Absorption and Desorption Reactions of YMgNi4-Based Alloys

Andreas Züttel, Loris Giovanni Lombardo, Wen Luo, Heena Yang

YMgNi4-based alloys exhibit reversible hydrogen absorption and desorption reactions at near room temperature. Here, we report that Co-substituted YMgNi4-based alloys exhibited higher hydrogen contents and lower hydrogen absorption and desorption reaction p ...

AMER CHEMICAL SOC2022

Direct CO2 Capture and Reduction to High-End Chemicals with Tetraalkylammonium Borohydrides

Andreas Züttel, Loris Giovanni Lombardo, Kun Zhao, Heena Yang, Youngdon Ko

We demonstrate the ability of tetraalkylammonium borohydrides to capture large amounts of CO2, even at low CO2 concentrations, and reduce it to formate under ambient conditions. These materials show CO2 absorption capacities up to 30 mmolCO2 g(-1) at room ...

Wiley-VCH Verlag GmbH2021

Decreasing the Stability of Borohydride with Ionic Liquids for Hydrogen Storage and Carbon Dioxide Conversion

Loris Giovanni Lombardo

The world needs to move from a fossil fuel to a renewable energy based society. With the increasing electricity production from wind and PV, short and long term energy storage are becoming one of challenge of the 21st century. While batteries are the prefe ...

EPFL2021

Crystal Structural Investigations for Understanding the Hydrogen Storage Properties of YMgNi4-Based Alloys

Andreas Züttel, Loris Giovanni Lombardo, Heena Yang

The hydrogen storage properties and crystal structures of YMgNi4-based alloys, which were synthesized from (2 - x)YNi2 and xMgNi(2) (0.6

2020

Imaging Catalysis: Operando Investigation of the CO2 Hydrogenation Reaction Dynamics by Means of Infrared Thermography

Andreas Züttel, Emad Oveisi, Emanuele Moioli, Loris Giovanni Lombardo, Kun Zhao, Robin Tobias Andreas Mutschler

Infrared thermography is a powerful tool to investigate the dynamic evolution of temperature in chemical reactions. The CO2 hydrogenation reaction is an ideal model reaction to assess the presented technique due to its high exothermicity. Various dynamic e ...

AMER CHEMICAL SOC2020