Personne
Diogo Filipe Mateus Rodrigues
Cette personne n’est plus à l’EPFL
Publications associées (19)
Revisiting the concept of extents for chemical reaction systems using an enthalpy balance
Dominique Bonvin, Diogo Filipe Mateus Rodrigues
For the investigation of complex reaction systems, it has been proposed to decouple the various rate processes using a linear time-invariant transformation that is constructed from knowledge of stoichiometry, reaction enthalpies, inlet compositions and tem ...
PERGAMON-ELSEVIER SCIENCE LTD2020Maximum-likelihood estimation of kinetic parameters via the extent-based incremental approach
Dominique Bonvin, Julien Léo Billeter, Diogo Filipe Mateus Rodrigues
For lumped homogeneous reaction systems, this paper presents a kinetic model identification scheme that provides maximum-likelihood parameter estimates and guarantees convergence to global optimality. The use of the extent-based incremental approach allows ...
PERGAMON-ELSEVIER SCIENCE LTD2019Dynamic Optimization of Reaction Systems via Exact Parsimonious Input Parameterization
Dominique Bonvin, Diogo Filipe Mateus Rodrigues
This paper discusses the use of parsimonious input parameterization for the dynamic optimization of reaction systems. This parameterization is able to represent the optimal inputs with only a few parameters. In the context of batch, semibatch, and continuo ...
AMER CHEMICAL SOC2019On reducing the number of decision variables for dynamic optimization
Dominique Bonvin, Diogo Filipe Mateus Rodrigues
This paper presents an input parameterization for dynamic optimization that allows reducing the number of decision variables compared to traditional direct methods. A small number of decision variables is likely to be beneficial for various applications su ...
2019Concept of Variants and Invariants for Reaction Systems, with Application to Estimation, Control and Optimization
The concept of reaction variants and invariants for lumped reaction systems has been known for several decades. Its applications encompass model identification, data reconciliation, state estimation and control using kinetic models. In this thesis, the con ...
EPFL2018On decoupling rate processes in chemical reaction systems - Methods and applications
Dominique Bonvin, Julien Léo Billeter, Michael Amrhein, Diogo Filipe Mateus Rodrigues
Models of chemical reaction systems can be complex as they need to include information regarding the reactions and the mass and heat transfers. The commonly used state variables, namely, concentrations and temperatures, express the interplay between many p ...
2018Generalized Incremental Model Identification for Chemical Reaction Systems
Dominique Bonvin, Julien Léo Billeter, Diogo Filipe Mateus Rodrigues, Adrien Oulevey
Identification of kinetic models and estimation of kinetic parameters in chemical reaction systems can be done using Incremental Model Identification (IMI). By using IMI, it is possible to separate the effect of the different reactions and thus investigate ...
2017On Decoupling Rate Processes in Chemical Reaction Systems - Methods and Applications
Dominique Bonvin, Julien Léo Billeter, Michael Amrhein, Sriniketh Srinivasan, Diogo Filipe Mateus Rodrigues
Models of chemical reaction systems can be complex as they need to include information regarding the reactions and the mass and heat transfers. The commonly used state variables, namely, concentrations and temperatures, express the interplay between many p ...
Elsevier2017Global Identification of Kinetic Parameters via the Extent-based Incremental Approach
Dominique Bonvin, Julien Léo Billeter, Diogo Filipe Mateus Rodrigues
The identification of reaction kinetics represents the main challenge in building models for reaction systems. The identification task can be performed via either simultaneous model identification (SMI) or incremental model identification (IMI), the latter ...
2017Concept and Applications of Extents in Chemical Reaction Systems
Dominique Bonvin, Julien Léo Billeter, Michael Amrhein, Sriniketh Srinivasan, Diogo Filipe Mateus Rodrigues
Models of chemical reaction systems can be quite complex as they typically include information regarding the reactions, the various transfers of heat and mass, as well as the effects of the inlet and outlet flows. It is well known that a linear transformat ...
2017