Publications de Suzanne Maria Jansze

Identification of a Heteroleptic Pd6L6L′6 Coordination Cage by Screening of a Virtual Combinatorial Library

Kay Severin, Rosario Scopelliti, Farzaneh Fadaei Tirani, Suzanne Maria Jansze, Rujin Li, Sylvain Alexandre Marie Sudan

The design of structurally defined heteroleptic coordination cages is a challenging task, and only few examples are known to date. Here we describe a selection approach that allowed the identification of a novel hexanuclear Pd cage containing two types of ...

2021

Two-Step Synthesis of Linear and Bent Dicarboxylic Acid Metalloligands with Lengths of up to 3 nm

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Suzanne Maria Jansze, Ophélie Marie Planes

Nanometer-sized polycarboxylate ligands are interesting building blocks for metallasupramolecular chemistry, but access to these compounds is often limited by complicated synthetic pathways. Here, we describe a simple two-step protocol, which allows prepar ...

2020

Molecular nanostructures based on polyfunctional clathrochelate complexes

Suzanne Maria Jansze

This thesis describes the design and synthesis of clathrochelate metalloligands for the construction of molecular nanostructures. The low synthetic effort, versatility and stability of the clathrochelate metalloligands makes them particularly suited to the ...

EPFL2019

Palladium-Based Metal–Ligand Assemblies: The Contrasting Behavior upon Addition of Pyridine or Acid

Kay Severin, Suzanne Maria Jansze

2019

Reversible disassembly of metallasupramolecular structures mediated by a metastable-state photoacid

Kay Severin, Suzanne Maria Jansze, Giacomo Cecot

The addition of a metastable-state photoacid to solutions containing metal–ligand assemblies renders the systems light responsive. Upon irradiation, proton transfer from the photoacid to the ligand is observed, resulting in disassembly of the metallasupram ...

2018

Inflating face-capped Pd6L8 coordination cages

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Laure Menin, Suzanne Maria Jansze

Royal Society of Chemistry2018

Clathrochelate Metalloligands in Supramolecular Chemistry and Materials Science

Kay Severin, Suzanne Maria Jansze

2018

PdII2L4-type coordination cages up to three nanometers in size

Rosario Scopelliti, Kay Severin, Suzanne Maria Jansze, Matthew David Wise

The utilization of large ligands in coordination-based self-assembly represents an attractive strategy for the construction of supramolecular assemblies more than two nanometers in size. However, the implementation of this strategy is hampered by the fact ...

2017

The Ligand Aspect Ratio as a Decisive Factor for the Self-Assembly of Coordination Cages

Rosario Scopelliti, Kay Severin, Philip Pattison, Euro Solari, Konstantin Zhurov, Suzanne Maria Jansze, Giacomo Cecot, Matthew David Wise, Alba Finelli

It is possible to control the geometry and the composition of metallasupramolecular assemblies via the aspect ratio of their ligands. This point is demonstrated for a series of iron- and palladium-based coordination cages. Functionalized clathrochelate com ...

2016