Publications de Nikita Drigo | EPFL Graph Search

The Role of Goldschmidt's Tolerance Factor in the Formation of A(2)BX(6) Double Halide Perovskites and its Optimal Range

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Nikita Drigo, Alexander Fedorovskiy

Vacancy-ordered double perovskites is a new branch of lead-free halide perovskites with properties promising for photovoltaic application. In this study, data about the crystal structure of 170 known A(2)BX(6) (X = I, Br, Cl, F) are collected and analyzed ...

2020

Molecular engineering of functional materials for optoelectronic applications

Nikita Drigo

Organic functional materials are indispensable components for the last generation of light-energy conversion devices. Photo- and electroactive small organic molecules constitute thin active (emitting, transporting, blocking, injecting etc.) layers of organ ...

EPFL2020

In Situ Analysis Reveals the Role of 2D Perovskite in Preventing Thermal-Induced Degradation in 2D/3D Perovskite Interfaces

Mohammad Khaja Nazeeruddin, Giulia Grancini, Valentin Ianis Emmanuel Queloz, Albertus Adrian Sutanto, Nikita Drigo, Rodrigo Szostak

Engineering 2D/3D perovskite interfaces is a common route to realizing efficient and stable perovskite solar cells. Whereas 2D perovskite’s main function in trap passivation has been identified and is confirmed here, little is known about its 2D/3D interfa ...

American Chemical Society (ACS)2020

Doped but Stable: Spirobisacridine Hole Transporting Materials for Hysteresis-Free and Stable Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Pascal Alexander Schouwink, Anne-Clémence Corminboeuf, Sanghyun Paek, Cristina Roldán Carmona, Albertus Adrian Sutanto, Hobeom Kim, Marius Franckevicius, Kun-Han Lin, Nikita Drigo

Four spirobisacridine (SBA) hole-transporting materials were synthesized and employed in perovskite solar cells (PSCs). The molecules bear electronically inert alkyl chains of different length and bulkiness, attached to in-plane N atoms of nearly orthogona ...

AMER CHEMICAL SOC2020

An Efficient Approach to Fabricate Air-Stable Perovskite Solar Cells via Addition of a Self-Polymerizing Ionic Liquid

Mohammad Khaja Nazeeruddin, Zhaofu Fei, Paul Joseph Dyson, Nikita Drigo, Rosario Scopelliti, Tom Theodorus Antonius Lummen, Farzaneh Fadaei Tirani, Yi Zhang, Cristina Roldán Carmona, Valentin Ianis Emmanuel Queloz

Despite the excellent photovoltaic properties achieved by perovskite solar cells at the laboratory scale, hybrid perovskites decompose in the presence of air, especially at high temperatures and in humid environments. Consequently, high-efficiency perovski ...

Wiley2020

Molecular Design and Operational Stability: Toward Stable 3D/2D Perovskite Interlayers

Mohammad Khaja Nazeeruddin, Pascal Alexander Schouwink, Anne-Clémence Corminboeuf, Sanghyun Paek, Kyung Taek Cho, Cristina Roldán Carmona, Hiroyuki Kanda, Marius Franckevicius, Hobeom Kim, Kun-Han Lin

Despite organic/inorganic lead halide perovskite solar cells becoming one of the most promising next-generation photovoltaic materials, instability under heat and light soaking remains unsolved. In this work, a highly hydrophobic cation, perfluorobenzylamm ...

2020

Dynamical evolution of the 2D/3D interface: a hidden driver behind perovskite solar cell instability

Mohammad Khaja Nazeeruddin, Pascal Alexander Schouwink, Sanghyun Paek, Giulia Grancini, Kyung Taek Cho, Valentin Ianis Emmanuel Queloz, Albertus Adrian Sutanto, Inés Garcia Benito, Nikita Drigo

Engineering two-/three-dimensional (2D/3D) perovskite solar cells is nowadays a popular strategy for efficient and stable devices. However, the exact function of the 2D/3D interface in controlling the long-term device behavior is still obscure. Here, we re ...

Royal Society of Chemistry2020

Retarding Thermal Degradation in Hybrid Perovskites by Ionic Liquid Additives

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Zhaofu Fei, Mounir Driss Mensi, Felix Daniel Bobbink, Cristina Roldán Carmona, Zhangjun Huang, Marius Franckevicius, Nikita Drigo, Rui Xia

Recent years have witnessed considerable progress in the development of solar cells based on lead halide perovskite materials. However, their intrinsic instability remains a limitation. In this context, the interplay between the thermal degradation and the ...

2019

Getting the Right Twist: Influence of Donor-Acceptor Dihedral Angle on Exciton Kinetics and Singlet-Triplet Gap in Deep Blue Thermally Activated Delayed Fluorescence Emitter

Mohammad Khaja Nazeeruddin, Anne-Clémence Corminboeuf, Antonio Prlj, Kun-Han Lin, Nikita Drigo

Here, a novel deep blue emitter SBABz4 for use in organic light-emitting diodes (OLED) is investigated. The molecular design of the emitter enables thermally activated delayed fluorescence (TADF), which we examine by temperature-dependent time-resolved ele ...

AMER CHEMICAL SOC2019

Multiarm and Substituent Effects on Charge Transport of Organic Hole Transport Materials

Mohammad Khaja Nazeeruddin, Kevin Sivula, Liang Yao, Antonio Prlj, Kun-Han Lin, Nikita Drigo, Han-Hee Cho

We explore several potential dopant-free triphenylamine-based hole transport materials for perovskite solar cells by combining two design strategies: (1) incorporation of multiple arms for mobility enhancement and (2) including Lewis bases that assist in d ...

2019