Publications de Luca Longetti | EPFL Graph Search

Deconvolution of the X-ray absorption spectrum of trans-1,3-butadiene with resonant Auger spectroscopy

Majed Chergui, Camila Bacellar Cases Da Silveira, Luca Longetti, Thomas Roland Barillot, Ludmila Maria Diniz Leroy

High-resolution carbon K-edge X-ray photoelectron, X-ray absorption, non-resonant and resonant Auger spectra are presented of gas phase trans-1,3-butadiene alongside a detailed theoretical analysis utilising nuclear ensemble approaches and vibronic models ...

Royal Soc Chemistry2024

Jahn-Teller effects in initial and final states: high-resolution X-ray absorption, photoelectron and Auger spectroscopy of allene

Majed Chergui, Camila Bacellar Cases Da Silveira, Luca Longetti, Rebecca Ann Ingle, Ludmila Maria Diniz Leroy, Thomas Roland Barillot, Daniel Hollas

Carbon K-edge resonant Auger spectra of gas-phase allene following excitation of the pre-edge 1s -> pi* transitions are presented and analysed with the support of EOM-CCSD/cc-pVTZ calculations. X-Ray absorption (XAS), X-ray photoelectron (XPS), valence ban ...

ROYAL SOC CHEMISTRY2023

Carbon K-edge x-ray emission spectroscopy of gas phase ethylenic molecules

Majed Chergui, Camila Bacellar Cases Da Silveira, Rebecca Ann Ingle, Luca Longetti, Thomas Roland Barillot

We report on the C K-edge x-ray absorption spectra and the resonant (RXES) and non-resonant (NXES) x-ray emission spectra of ethylene, allene and butadiene in the gas phase. The RXES and NXES show clear differences for the different molecules. Overall both ...

IOP Publishing2022

Ultrafast photoelectron spectroscopy of photoexcited aqueous ferrioxalate

Majed Chergui, Michele Puppin, Frank van Mourik, Christopher Alexander Arrell, José Javier Pancracio Ojeda Andara, Luca Longetti, Thomas Roland Barillot

The photochemistry of metal-organic compounds in solution is determined by both intra- and inter-molecular relaxation processes after photoexcitation. Understanding its prime mechanisms is crucial to optimise the reactive paths and control their outcome. H ...

2021

Ultrafast Photoelectron and Optical Spectroscopies of Photoinduced Processes in Molecular Systems in Solution

Luca Longetti

Investigating molecular excitations with femtosecond time resolution is of pivotal importance to understand the out-of-equilibrium processes taking place in molecular systems upon light absorption. The photochemistry of solvated species is heavily determin ...

EPFL2020

Photoemission from non-polar aromatic molecules in the gas and liquid phase

Majed Chergui, Frank van Mourik, Christopher Alexander Arrell, Lars-Hendrik Mewes, José Javier Pancracio Ojeda Andara, Jakob Grilj, Luca Longetti

The photoelectron spectra of both liquid and gas phase aromatic molecules are reported. The spectra were obtained using a 34.1 eV source produced by high harmonic generation and analysed with the help of high-level ab initio simulations using the reflectio ...

ROYAL SOC CHEMISTRY2020

Harmonium: An Ultrafast Vacuum Ultraviolet Facility

Majed Chergui, Marco Grioni, Marcel Drabbels, Frank van Mourik, Alberto Crepaldi, Christopher Alexander Arrell, Gianmarco Gatti, José Javier Pancracio Ojeda Andara, Luca Longetti, Andrew Daniel Bonnar Clark

Harmonium is a vacuum ultraviolet (VUV) photon source built within the Lausanne Centre for Ultrafast Science (LACUS). Utilising high harmonic generation, photons from 20-110 eV are available to conduct steady-state or ultrafast photoelectron and photoion s ...

Swiss Chemical Soc2017

Charge-transfer and impulsive electronic-to-vibrational energy conversion in ferricyanide: ultrafast photoelectron and transient infrared studies'

Majed Chergui, Christopher Alexander Arrell, José Javier Pancracio Ojeda Andara, Luca Longetti

The photophysics of ferricyanide in H2O, D2O and ethylene glycol was studied upon excitation of ligand-to-metal charge transfer (LMCT) transitions by combining ultrafast photoelectron spectroscopy (PES) of liquids and transient vibrational spectroscopy. Up ...

Royal Society of Chemistry2017