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An asymmetric synthesis of (+)-stephadiamine has been accomplished featuring (a) an enantioselective dearomatizative Michael addition to generate a quaternary stereocenter; (b) a domino sequence involving reductive generation of nitrone from γ-nitro ketone ...
The snow is one of the most important water resources in grassland in northern and western China, while the wind blowing snow due to the strong wind there is a common phenomenon, which can lead to heavy disasters to harm the local animal husbandry and tran ...
Snow is one of the most active elements on the earth, which is an important mass source of polar ice sheets and alpine glaciers, as well as a main supply for the runoff. Its distribution and evolution have a great impact on global hydrological cycle, ecosy ...
We report herein the enantioselective total synthesis of three monoterpene indole alkaloids, namely, (+)-alstilobanine C, (+)-undulifoline, and (-)-alpneumine H. The key features of our synthesis include: a) introduction of chirality via enantioselective d ...
Controlling the cis C20/C21 relative stereochemistry remains an unsolved issue in the synthesis of eburnane-type indole alkaloids. Provided herein is a simple solution to this problem by developing a unified and diastereoselective synthesis of four represe ...
Elegant asymmetric synthesis of hasubanan alkaloids have been developed over the past decades. However, a divergent approach leading to all three sub-classes of this family of natural products remains unknown. We report herein the realization of such an en ...