Yu Rao

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Publications associées (13)

H-1 Hyperpolarization of Solutions by Overhauser Dynamic Nuclear Polarization with C-13-H-1 Polarization Transfer

David Lyndon Emsley, Yu Rao, Pinelopi Moutzouri, Amrit Venkatesh

Dynamic nuclear polarization (DNP) is a method that can significantly increase the sensitivity of nuclear magnetic resonance. The only effective DNP mechanism for in situ hyperpolarization in solution is Overhauser DNP, which is inefficient for H-1 at high ...

2022

Open and Closed Radicals: Local Geometry around Unpaired Electrons Governs Magic-Angle Spinning Dynamic Nuclear Polarization Performance

David Lyndon Emsley, Gabriele Stevanato, Yu Rao, Dominik Józef Kubicki, Moreno Lelli, Manuel Cordova, Georges Guévork Jean-Jacques Menzildjian

The development of magic-angle spinning dynamic nuclear polarization (MAS DNP) has allowed atomic-level characterization of materials for which conventional solid-state NMR is impractical due to the lack of sensitivity. The rapid progress of MAS DNP has be ...

2020

Dynamic Nuclear Polarization Enhancement of 200 at 21.15 T Enabled by 65 kHz Magic Angle Spinning

David Lyndon Emsley, Yu Rao, Pierrick Berruyer, Moreno Lelli, Gabriele Stevanato, Snaedis Björgvinsdóttir, Andrea Bertarello

Solid-state nuclear magnetic resonance under magic angle spinning (MAS) enhanced with dynamic nuclear polarization (DNP) is a powerful approach to characterize many important classes of materials, allowing access to previously inaccessible structural and d ...

2020

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Open and Closed Radicals: Local Geometry around Unpaired Electrons Governs Magic-Angle Spinning Dynamic Nuclear Polarization Performance

David Lyndon Emsley, Gabriele Stevanato, Yu Rao, Dominik Józef Kubicki, Moreno Lelli, Manuel Cordova, Georges Guévork Jean-Jacques Menzildjian

2020

H-1 Hyperpolarization of Solutions by Overhauser Dynamic Nuclear Polarization with C-13-H-1 Polarization Transfer

David Lyndon Emsley, Yu Rao, Pinelopi Moutzouri, Amrit Venkatesh

2022

Dynamic Nuclear Polarization Enhancement of 200 at 21.15 T Enabled by 65 kHz Magic Angle Spinning

David Lyndon Emsley, Yu Rao, Pierrick Berruyer, Moreno Lelli, Gabriele Stevanato, Snaedis Björgvinsdóttir, Andrea Bertarello

2020