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Pierrick Berruyer

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Publications associées (23)

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Quantification of magic angle spinning dynamic nuclear polarization NMR spectra

David Lyndon Emsley, Pierrick Berruyer, Andrea Bertarello

Dynamic nuclear polarization (DNP) allows to dramatically enhance the sensitivity of magic angle spinning nuclear magnetic resonance (MAS NMR). DNP experiments usually rely on the detection of low-γ nuclei hyperpolarized from 1H with the use of cross polar ...

2021

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Despite use of blended cements containing significant amounts of aluminum for over 30 years, the structural nature of aluminum in the main hydration product, calcium aluminate silicate hydrate (C-A-S-H), remains elusive. Using first-principles calculations ...

AMER CHEMICAL SOC2020

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Solid-state nuclear magnetic resonance under magic angle spinning (MAS) enhanced with dynamic nuclear polarization (DNP) is a powerful approach to characterize many important classes of materials, allowing access to previously inaccessible structural and d ...

2020

Sensitivity Enhancements in Lithium Titanates by Incipient Wetness Impregnation DNP NMR

David Lyndon Emsley, Michael Allan Hope, Pierrick Berruyer, Pinelopi Moutzouri, Snaedis Björgvinsdóttir

Solid-state NMR spectroscopy is a widely used method for investigating structural and electronic properties of inorganic materials, but its use is often limited by low sensitivity. Here, we show how solvent-generated dynamic nuclear polarization can be use ...

AMER CHEMICAL SOC2020

Topology of Pretreated Wood Fibers Using Dynamic Nuclear Polarization

David Lyndon Emsley, Jeremy Luterbacher, Arthur César Pinon, Pierrick Berruyer, Jasmine Viger-Gravel, Wu Lan, Michel Bardet

In the continuously developing field of lignocellulosic biomass, high-yield lignin depolymerization processes are sought to optimize its productivity and profitability. Recently, formaldehyde stabilization during lignin extraction and biomass pretreatment ...

AMER CHEMICAL SOC2019

Dynamic nuclear polarization (DNP)-enhanced solid-state NMR spectroscopy under magic-angle spinning has recently emerged as a unique analytical method to probe surfaces at atomic resolution. In this article, we first describe the basic principles of dynami ...

WILEY2018

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Hyperpolarization by dynamic nuclear polarization relies on the microwave irradiation of paramagnetic radicals dispersed in molecular glasses to enhance the nuclear magnetic resonance (NMR) signals of target molecules. However, magnetic or chemical interac ...

2017

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Dynamic nuclear polarization (DNP) has recently emerged as a tool to enhance the sensitivity of solid-state NMR experiments. However, so far high enhancements (>100) are limited to relatively low magnetic fields, and DNP at fields higher than 9.4 T signifi ...

American Chemical Society2017

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We show how dynamic nuclear polarization (DNP) NMR can be used in combination with models for polarization dynamics to determine the domain sizes in complex materials. By selectively doping a source component with radicals and leaving the target undoped, w ...

2017

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Aqueous acrylamide gels can be used to provide dynamic nuclear polarization (DNP) NMR signal enhancements of around 200 at 9.4 T and 100 K. The enhancements are shown to increase with crosslinker concentration and low concentrations of the AMUPol biradical ...

2017