Publications de Aditya Mishra | EPFL Graph Search

Stabilization of highly efficient perovskite solar cells with a tailored supramolecular interface

Michael Graetzel, Shaik Mohammed Zakeeruddin, David Lyndon Emsley, Felix Thomas Eickemeyer, Chenxu Zhao, Michael Allan Hope, Aditya Mishra, Masaud Hassan S Almalki, Anurag Krishna, Zhiwen Zhou

The presence of defects at the interface between the perovskite film and the carrier transport layer poses significant challenges to the performance and stability of perovskite solar cells (PSCs). Addressing this issue, we introduce a dual host-guest (DHG) ...

Nature Research2024

Axial-Equatorial Halide Ordering in Layered Hybrid Perovskites from Isotropic-Anisotropic 207Pb NMR

David Lyndon Emsley, Ümmügülsüm Günes, Michael Allan Hope, Manuel Cordova, Aditya Mishra

Bandgap-tuneable mixed-halide 3D perovskites are of interest for multi-junction solar cells, but suffer from photoinduced spatial halide segregation. Mixed-halide 2D perovskites are more resistant to halide segregation and are promising coatings for 3D per ...

Wiley-VCH Verlag GmbH2024

Light-Induced Metallic and Paramagnetic Defects in Halide Perovskites from Magnetic Resonance

David Lyndon Emsley, Michael Allan Hope, Aditya Mishra

Halide perovskites are promising next-generation solar cell materials, but their commercialization is hampered by their propensity to degrade under operating conditions, particularly under heat, humidity, and light. Identifying degradation products and lin ...

2024

Hydrogen Diffusion in Hybrid Perovskites from Exchange NMR

David Lyndon Emsley, Aditya Mishra

Ion migration is an important phenomenon affecting the performance of hybrid perovskite solar cells. It is particularly challenging, however, to disentangle the contribution of H+ diffusion from that of other ions, and the atomic-scale mechanism remains un ...

AMER CHEMICAL SOC2024

Light-Induced Halide Segregation in 2D and Quasi-2D Mixed-Halide Perovskites

David Lyndon Emsley, Manuel Cordova, Michael Allan Hope, Aditya Mishra

Photoinduced halide segregation hinders widespread application of three-dimensional (3D) mixed-halide perovskites. Much less is known about this phenomenon in lower-dimensional systems. Here, we study photoinduced halide segregation in lower-dimensional mi ...

AMER CHEMICAL SOC2023

Cooperative passivation of perovskite solar cells by alkyldimethylammonium halide amphiphiles

Michael Graetzel, Shaik Mohammed Zakeeruddin, David Lyndon Emsley, Ursula Röthlisberger, Felix Thomas Eickemeyer, Lukas Pfeifer, Thomas Paul Baumeler, Mathias Dankl, Nikolaos Lempesis, Ulf Anders Hagfeldt

2023

Dynamic Nuclear Polarization of Inorganic Halide Perovskites

David Lyndon Emsley, Dominik Józef Kubicki, Gabriele Stevanato, Michael Allan Hope, Aditya Mishra

NMR, EPR, XRD datasets and SEM image for the research article titled "Dynamic Nuclear Polarization of Inorganic Halide Perovskites". For further details see the readme.txt file. ...

Zenodo2023

A Complete Picture of Cation Dynamics in Hybrid Perovskite Materials from Solid-State NMR Spectroscopy

Michael Graetzel, David Lyndon Emsley, Michael Allan Hope, Aditya Mishra

The organic cations in hybrid organic-inorganic perovskites rotate rapidly inside the cuboctahedral cavities formed by the inorganic lattice, influencing optoelectronic properties. Here, we provide a complete quantitative picture of cation dynamics for for ...

AMER CHEMICAL SOC2023

Optically Enhanced Solid-State H-1 NMR Spectroscopy

David Lyndon Emsley, Jean-Philippe Ansermet, Federico De Biasi, Saumya Badoni, Dominik Józef Kubicki, Aaron James Rossini, Jonas Milani, Gabriele Stevanato, Michael Allan Hope, Moreno Lelli

Low sensitivity is the primary limitation to extendingnuclearmagnetic resonance (NMR) techniques to more advanced chemical andstructural studies. Photochemically induced dynamic nuclear polarization(photo-CIDNP) is an NMR hyperpolarization technique where ...

AMER CHEMICAL SOC2023

Dynamic Nuclear Polarization of Inorganic Halide Perovskites

David Lyndon Emsley, Dominik Józef Kubicki, Gabriele Stevanato, Michael Allan Hope, Aditya Mishra

The intrinsic low sensitivity of nuclear magnetic resonance (NMR) experiments limits their utility for structure determination of materials. Dynamic nuclear polarization (DNP) under magic angle spinning (MAS) has shown tremendous potential to overcome this ...

2023